Abstract
Stages in the development of a protective α-Al2O3 scale on a Ni-15Cr-6Al (wt.%) alloy have been examined. It is shown that prior to the formation of a continuous α-Al2O3 layer, a transient stage of oxidation occurs that consists of a rapid uptake of oxygen with conversion of a thin surface layer of alloy to predominantly spinel and the subsequent development of a discrete layer of Cr2O3. It is also shown that during the transient period of oxidation metastable phases of aluminum oxide are formed which transform to α-Al2O3 upon incorporation into the external oxide scale.
Similar content being viewed by others
References
C. S. Giggins and F. S. Pettit,J. Electrochem. Soc. 118, 1782 (1971).
N. A. Nielsen, Symposium Corrosion Fundamentals, University of Tenn. (1965), p. 148.
F. S. Pettit, R. A. Yinger, and J. B. Wagner, Jr.,Acta Met. 8, 617 (1960).
M. F. Ashby and G. C. Smith,J. Inst. Met. 91, 182 (1962–1963).
C. Wagner,Corrosion Sci. 5 (11), 751 (1965).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kear, B.H., Pettit, F.S., Fornwalt, D.E. et al. On the transient oxidation of a Ni-15Cr-6Al alloy. Oxid Met 3, 557–569 (1971). https://doi.org/10.1007/BF00605003
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00605003