Abstract
The anodic dissolution of gold in concentrated potassium cyanide solution was studied. Four regions of passivation were observed: at -0·6 V, +0·1 V, +0·4 V and +0·7 V versus SCE. The passive phenomena were explained in terms of the interaction of hydroxyl ions with the gold surface.
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N. Hedley and H. Tabachnik,Internat. Tech. Bull. 31 Wayne, New Jersey (1968).
E. M. Wise, ‘Gole, Recovery, Properties and Application’, D. Van Nostrand Co., New Jersey (1965).
F. Habashi,J. Chem. Education 42 (1965) 318.
T. P. Pan and C. C. Wan, to be published inJ. Electrochem.
K. J. Cathro and D. F. A. Koch,J. Electrochem. Soc. 111 (1964) 1416.
D. M. MacArthur,J. Electrochem. Soc. 119 (1972) 672.
A. Bewick and J. Robinson,Surf. Sci. 55 (1976) 349.
Idem, J. Electroanalyt. Chem. 60 (1975) 163.
El Yeager, US NTIS, AD-A Rep. (1975) AD-A011905, 34.
J. D. E. McIntyre, ‘Advances in Electrochemistry and Electrochemical Engineering’ Vol. 9, John Wiley, New York (1973).
W. Roseveare and T. Buehrer,J. Amer. Chem. Soc. 49 (1927) 1221.
S. Barnartt,J. Electrochem. Soc. 106 (1959) 722.
A. N. Lebedev and I. A. Kakovskii,Electrokhim. 2 (1966) 1079.
K. Ogura and K. Nagasaki,J. Electrochem. Soc. 118 (1971) 531.
R. P. Frankenthal and D. E. Thompson,ibid 123 (1976) 799.
J. H. Gallego and C. E. Cstellano,J. Electroanalyt. Chem. 66 (1975) 207.
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Pan, T.P., Wan, C.C. Anodic behaviour of gold in cyanide solution. J Appl Electrochem 9, 653–655 (1979). https://doi.org/10.1007/BF00610956
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DOI: https://doi.org/10.1007/BF00610956