Abstract
This paper deals with an experimental study of copper deposition in fluidized bed electrodes from acidified aqueous solutions containing copper. Overpotential distributions are determined and the amount of copper deposited at various levels within the electrodes is also measured. Experiments with long duration times allow the variations of current efficiency for recovery to be obtained as a function of current density and fixed bed thickness. These variations could be explained by the existence of dissolution zones within the electrodes.
Similar content being viewed by others
References
M. Fleischmann, F. Goodridge and J. R. Backhurst, Brit. Pat. 1194181 (1970).
F. Coeuret, P. Le Goff and F. Vergnes, French Pat. 1500269 (1967).
J. R. Backhurst, J. M. Coulson, F. Goodridge and R. E. Plimley,J. Electrochem. Soc. 116 (1969) 1600.
M. Fleischmann, J. W. Oldfield and D. F. Porter,J. Electroanal. Chem. 29 (1971) 241.
M. Fleischmann, J. W. Oldfield and L. Tennakoon,J. Appl. Electrochem. 1 (1971) 103.
F. Goodridge, D. I. Holden, H. D. Murray and R. F. Plimley,Trans. Inst. Chem. Engrs. 49 (1971) 128.
Idem, ibid 49 (1971) 137.
J. N. Hiddleston and A. F. Douglas,Nature, Lond. 218 (1968) 601.
T. Berent, I. Fells and R. Mason,ibid 223 (1969) 1054.
J. R. Backhurst, F. Goodridge, R. E. Plimley and M. Fleischmann,ibid 221 (1969) 55.
T. Berent, R. Mason and I. Fells,J. Appl. Chem. Biotechnol. 21 (1971) 71.
F. Goodridge and B. M. Ismail, Electrochemical Engineering Symposium, March 30–April 1, (1971) Newcastle-upon-Tyne, Great Britain.
J. N. Hiddleston and A. F. Douglas,Electrochim. Acta 15 (1970) 431.
L. J. J. Janssen,ibid 16 (1971) 151.
D. S. Flett,Chem. Ind. 51 (1971) 300.
Idem, ibid 52 (1972) 983.
J. A. E. Wilkinson and K. P. Haines,Trans. Inst. Min. Metall. Section C,81 (790) (1972) 157.
A. J. Monhemius and P. L. N. Costa,Hydrometallurgy 1 (1975) 183.
F. Coeuret,Electrochim. Acta 21 (1976) 203.
S. Germain and F. Goodridge,ibid 21 (1976) 545.
M. Fleischmann and J. W. Oldfield,J. Electroanal. Chem. 29 (1971) 211.
Idem, ibid 29 (1971) 241.
F. Goodridge,Chem. Process. Eng. 49 (2) Feb. (1968) 93–95 and 100.
P. Le Goff, F. Vergnes, F. Coeuret and J. Bordet,Ind. and Eng. Chem. 61 (1969) 8.
T. Z. Fahildy,Canad. J. Chem. Eng. 51 (1973) 521.
J. A. E. Wilkinson,Trans. Inst. Metal Finishing 49 (Spring 1971) 16.
D. N. Bennion and J. Newman,J. Appl. Electrochem 2 (1972) 113.
F. Goodridge,Hydrometallurgy 1 (1976) 393.
F. Coeuret, D. Hutin and A. Gaunand,J. Appl. Electrochem. 6 (1976) 417.
M. Paulin, D. Hutin and F. Coeuret,J. Electrochem. Soc. 124 (1977) 180.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hutin, D., Coeuret, F. Experimental study of copper deposition in a fluidized bed electrode. J Appl Electrochem 7, 463–471 (1977). https://doi.org/10.1007/BF00616757
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00616757