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Electrocoating from molten salts

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Abstract

Electrolytic deposition processes from molten salt baths, i.e. metalliding and electroplating, for coating metal or alloy substrates are described. An outline of the general experimental techniques employed in molten salts and the influence of various factors such as impurities, cation valency, nature of the solvent, stability of complex ions, temperature, current density, kinetics, and additives, on the electrolytic processes are discussed. A review of the current status of electrodeposited coatings from molten salts, with special reference to diffusion coatings on metal and alloy surfaces, is presented. The available physical, chemical, and mechanical properties of the coatings thus formed and their applications are summarized. Some suggestions are made to show the directions in which further research in this field is necessary.

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References

  1. N. C. Cook,Sci. Amer. 221 (1969) 38.

    Google Scholar 

  2. M. H. Hansen, ‘Constitution of binary alloys’, McGraw-Hill, New York (1958).

    Google Scholar 

  3. R. P. Elliott, ‘Constitution of binary alloys’, Supplement, McGraw-Hill, New York (1965).

    Google Scholar 

  4. K. Matiasovsky, Z. Lubyova and V. Danek,Electrodepos. Surface Treat. 1 (1972) 43.

    Google Scholar 

  5. G. W. Mellors and S. Senderoff,J. Electrochem. Soc. 112 (1965) 266.

    Google Scholar 

  6. S. Senderoff, in ‘Modern electroplating’ (edited by F. A. Lowen-Heim) John Wiley and Sons Inc., New York (1974) pp. 473–85.

    Google Scholar 

  7. J. Wurm,European ConferenceDevelopment of Molten Salts Applications’, Geneva, Battelle (1973) pp. 62–9.

    Google Scholar 

  8. M. A. Steinberg and R. G. McAllen, Canadian Patent 563 495 (1958).

    Google Scholar 

  9. M. E. Sibert and J. T. Burwell, Canadian Patent 554 772 (1958).

    Google Scholar 

  10. Horizons Inc., British Patent 788 804, 1958;Chem. Abstr. 52 (1958) 8801.

  11. American Electro-Metal Corp., British Patent 659 927 (1951).

  12. N. C. Cook, presented atNATO Advanced Study Institute Conference ‘The Science and Technology of Surface Coatings’, Imperial College of Science and Technology, London (1972).

    Google Scholar 

  13. N. C. Cook,Proceedings of International Conference ‘Protection Against Corrosion by Metal Finishing’ Basel, (1966) 151.

  14. J. C. Withers, J. E. Perry and B. A. Fosnocht, in ‘Techniques of metals research’, Vol. VII, (edited by R. F. Burnshah), Interscience, New York (1972) pp. 203–27.

    Google Scholar 

  15. C. A. Hampel (Ed.), ‘The encyclopedia of electrochemistry’, Reinhold, New York (1964).

    Google Scholar 

  16. S. Senderoff and G. W. Mellors,Science 153 (1966) 1475.

    Google Scholar 

  17. S. Senderoff,Metall. Revs. 11 (1966) 97.

    Google Scholar 

  18. D. Inman and R. Spencer, in ‘Advances in extractive metallurgy and refining’ (edited by M. J. Jones) London, IMM (1972) pp. 413–24.

    Google Scholar 

  19. J. C. L. Legey,Metal ABM 32 (1976) 41.

    Google Scholar 

  20. S. P. Antonov, L. E. Ivanovskii and O. S. Petenev,Prot. Met. 9 (1973) 500.

    Google Scholar 

  21. D. Inman and S. H. White,International Symposium ‘Molten Salt Electrolysis in Metal Production’, Grenoble, IMM (1977) pp. 51–61.

    Google Scholar 

  22. D. Inman,European Conference on Development of Molten Salts Applications, Geneva, Battelle (1973) pp. 58–61.

    Google Scholar 

  23. F. R. Collins,Iron Age 169 (1952) 100.

    Google Scholar 

  24. E. J. Smith and M. G. Vucich, US Patent 3007 854 (1961).

  25. R. C. Howie and D. W. MacMillan,J. Appl. Electrochem. 2 (1972) 217.

    Google Scholar 

  26. B. Nayak and M. M. Misra,J. Appl. Electrochem. 7 (1977) 45.

    Google Scholar 

  27. G. W. Mellors and S. Senderoff,Plating 51 (1964) 972.

    Google Scholar 

  28. A. D. Graves and D. Inman,Electroplating Metal Finish. 19 (1966) 314.

    Google Scholar 

  29. A. Weser,Electroplating Metal Finish.29 (1976) 6.

    Google Scholar 

  30. Plat. Met. Rev. 19 (1975) 15.

  31. R. J. Fabian,Materials and Methods 45 (1957) 121.

    Google Scholar 

  32. Yu. V. Baymakov,Russ. Met. (1970) 66.

  33. G. J. Hills, D. J. Schiffrin and J. Thompson,Electrochim. Acta 19 (1974) 657.

    Google Scholar 

  34. C. Decroly, C. Mukhtar and R. Winand,J. Electrochem. Soc. 115 (1968) 905.

    Google Scholar 

  35. Yu. V. Baymakov and N. V. Polyakov, ‘Physical chemistry of fused salts’ (in Russian). Metallurgiya, Moscow (1965) p. 262.

    Google Scholar 

  36. H. Gerischer,Proceedings International Conference on Protection Against Corrosion by Metal Finishing, Basel (1966) pp. 11–23.

  37. H. Fischer,Proceedings International Conference on Protection Against Corrosion by Metal Finishing, Basel (1966) pp. 24–38.

  38. N. Ibl,Proceedings International Conference on Protection Against Corrosion by Metal Finishing, Basel (1966) pp. 48–61.

  39. R. S. Sethi, unpublished work.

  40. D. Inman, R. S. Sethi and R. Spencer,J. Electroanalyt. Chem. 29 (1971) 137.

    Google Scholar 

  41. A. D. Graves, G. J. Hills and D. Inman,Adv. Electrochem. Engng. 4 (1966) 117.

    Google Scholar 

  42. A. D. Graves and D. Inman, in ‘Electromotive force measurements in high temperature systems’, (edited by C. B. Alcock) IMM, London (1968) pp. 183–97.

    Google Scholar 

  43. G. Mamantov, in ‘Molten salts characterization and analysis’, (edited by G. Mamantov) Dekker, New York (1969) pp. 529–61.

    Google Scholar 

  44. Yu. V. Baymakov and M. M. Vetyukov, ‘Electrolysis of molten salts’ (in Russian). Metallurgiya, Moscow (1966).

    Google Scholar 

  45. A. N. Baraboshkin, ‘Physical chemistry and electrochemistry of fused salts and slags’ (in Russian) Khimiya, Leningrad (1968) p. 185.

    Google Scholar 

  46. Yu. V. Baymakov and I. V. Tomskikh, ‘Physical chemistry and electrochemistry of fused salts and slags’ (in Russian). Khimiya, Leningrad (1968) p. 52.

    Google Scholar 

  47. M. Galopin and J. S. Daniel,Electrodepos. Surface Treat. 3 (1975) 1.

    Google Scholar 

  48. R. S. Sethi and M. J. P. McBurney, unpublished work.

  49. G. J. Hills, D. J. Schiffrin and J. Thompson,Electrochem. Soc. 120 (1973) 157.

    Google Scholar 

  50. G. W. Mellors and S. Senderoff,University of Pittsburgh Conference on Applications of Fundamental Thermodynamics to Metallurgical Processes, (edited by G. R. Fitterer) Gordon Brench, New York (1967) pp. 81–103.

    Google Scholar 

  51. H. C. Gaur and R. S. Sethi,Indian J. Chem. 5 (1967) 485.

    Google Scholar 

  52. C. E. Bamberger, ‘Experimental techniques in molten fluoride chemistry’ (edited by J. Braunstein, G. Mamantov and G. P. Smith) Plenum Press, New York, Vol. 3 (1975) pp. 177–248.

    Google Scholar 

  53. H. C. Gaur, H. L. Jindal and R. S. Sethi,Electrochim. Acta 15 (1970) 845.

    Google Scholar 

  54. H. C. Gaur and R. S. Sethi,J. Electroanalyt. Chem. 7 (1964) 474.

    Google Scholar 

  55. J. P. Pemsleret al., ‘Molten salts’. The Electrochemical Society, Princeton, New Jersey (1976).

    Google Scholar 

  56. H. A. Laitinen, W. S. Ferguson and R. A. Osteryoung,J. Electrochem. Soc. 104 (1957) 516.

    Google Scholar 

  57. N. C. Cook, US Patents 3024 175 (Be); 3024 176 (B); 3489 537 (Al); 3514 272 (V).

  58. D. W. Townsend, in ‘Molten salts’ (edited by J. P. Pemsleret al.) The Electrochemical Society, Princeton, New Jersey (1976) pp. 388–99.

    Google Scholar 

  59. R. K. Jainet al., J. Electroanalyt. Chem. 78 (1977) 1.

    Google Scholar 

  60. R. K. Jain, H. C. Gaur and B. J. Welch,J. Electroanalyt. Chem. 79 (1977) 211.

    Google Scholar 

  61. P. Delahay, ‘New instrumental methods in electrochemistry’, Interscience, New York (1954).

    Google Scholar 

  62. J. Albery, ‘Electrode kinetics’ Clarendon Press, Oxford (1975).

    Google Scholar 

  63. G. W. Mellors and S. Senderoff,J. Electrochem. Soc. 113 (1966) 60.

    Google Scholar 

  64. N. Godshall,J. Electrochem. Soc. 123 (1976) 137 C.

    Google Scholar 

  65. N. S. Greyver, N. P. Sazhin and I. A. Strigin, ‘Fundamentals of metallurgy: rare metals’, Metallurgia (1967).

  66. S. M. Selis,J. Phys. Chem. 72 (1968) 1442.

    Google Scholar 

  67. A. D. Graves and D. Inman,J. Electroanalyt. Chem. 25 (1970) 357.

    Google Scholar 

  68. G. W. Mellors and S. Senderoff,J. Electrochem. Soc. 112 (1965) 840.

    Google Scholar 

  69. S. Senderoff and G. W. Mellors,J. Electrochem. Soc. 113 (1966) 66.

    Google Scholar 

  70. S. Senderoff and G. W. Mellors,J. Electrochem. Soc. 114 (1967) 586.

    Google Scholar 

  71. T. B. Reddy,Electrochem. Technol 1 (1963) 325.

    Google Scholar 

  72. D. Inman, A. D. Graves and R. S. Sethi,Electrochemistry 1 (1970) 166.

    Google Scholar 

  73. D. Inman, A. D. Graves and A. A. Nobile,Electrochemistry 2 (1972) 61.

    Google Scholar 

  74. D. Inmanet al., Electrochemistry 4 (1974) 78.

    Google Scholar 

  75. D. Inman and S. H. White,Ann. Rep. Progr. Chem. 62 (1966) 106.

    Google Scholar 

  76. J. Braunstein, G. Mamantov and G. P. Smith (Eds.), ‘Advances in molten salt chemistry’, Plenum Press, New York, Vol. 1 (1972), Vol. 2 (1973), Vol. 3 (1975).

    Google Scholar 

  77. Yu. K. Delimarskiiet al., ‘Electrolytic tin plating from salt metals’. Naukova Dumka, Kiev (1967).

    Google Scholar 

  78. I. F. Danzig, R. M. Dempsey and A. B. La Conti,CorrosionNACE 27 (1971) 55.

    Google Scholar 

  79. A. R. Stetson,Mat. Design Eng. 57 (1963) 81.

    Google Scholar 

  80. A. R. Stetson, US Patent 3024 174 (1962).

  81. H. C. Brookeset al., Trans. Inst. Metal Finish. 54 (1976) 191.

    Google Scholar 

  82. V. Danek and K. Matiasovsky,Surf. Technol. 5 (1977) 65.

    Google Scholar 

  83. P. J. Bowles and P. C. Newdick,Electroplating Metal Finish. 24 (1971) 6.

    Google Scholar 

  84. A. Bonomi, H. Giess and C. Gentaz,Electrodepos. Surface Treat. 1 (1973) 419.

    Google Scholar 

  85. P. Fellner and K. Matiasovsky,Electrodepos. Surface Treat. 3 (1975) 235.

    Google Scholar 

  86. N. Petrescuet al., Rev. Roumaine Chim. 18 (1973) 1853.

    Google Scholar 

  87. E. J. Frazer, K. E. Anthony and B. J. Welch,Electrodepos. Surface Treat. 3 (1975) 169.

    Google Scholar 

  88. G. Lehnert and H. W. Meinhardt,Electrodepos. Surface Treat. 1 (1972) 189.

    Google Scholar 

  89. Z. Lubyovaet al., Surf. Technol. 5 (1977) 479.

    Google Scholar 

  90. S. Senderoff and G. W. Mellors,J. Electrochem. Soc. 114 (1967) 556.

    Google Scholar 

  91. G. W. Mellors and S. Senderoff,J. Electrochem Soc. 118 (1971) 220.

    Google Scholar 

  92. G. W. Mellors and S. Senderoff,J. Electrochem. Soc. 112 (1965) 642.

    Google Scholar 

  93. G. W. Mellors and S. Senderoff, British Patent 1007 930 (1963).

    Google Scholar 

  94. G. W. Mellors and S. Senderoff, Canadian Patent 688 546 (1963).

    Google Scholar 

  95. G. W. Mellors and S. Senderoff, US Patent 3398 068 (1968).

    Google Scholar 

  96. G. W. Mellors and S. Senderoff, US Patent 3444 058 (1969).

    Google Scholar 

  97. S. Senderoff and A. Brenner,J. Electrochem. Soc. 101 (1954) 16.

    Google Scholar 

  98. D. Inman, J. C. Legey and R. Spencer,J. Electroanalyt. Chem. 61 (1975) 289.

    Google Scholar 

  99. D. Inman,Chem. Ind. 9 (1975) 385.

    Google Scholar 

  100. S. Tokumoto, E. Tanaka and K. Ogisu,J. Met. 27 (1975) 18.

    Google Scholar 

  101. S. Tokumoto and E. Tanaka, US Patent 3662 047.

  102. C. W. Balke,Ind. Engng. Chem. 27 (1935) 1166.

    Google Scholar 

  103. B. H. Eckstein and R. F. Ashton, Canadian Patent 742 190 (1966).

    Google Scholar 

  104. G. L. Davis and C. H. R. Gentry,Metall. 53 (1956) 3.

    Google Scholar 

  105. V. S. Balikhin and V. A. Pavlovskii,Tsvet. Metally 3 (1975) 76.

    Google Scholar 

  106. D. Schlain, F. X. McCawley and G. R. Smith, ‘Electrodeposition of titanium diboride coating’. Rep. Invest. No. 8140, US Department of Interior, Bureau of Mines, Washington DC, 20 240 (1976) 1–22.

    Google Scholar 

  107. D. Schlain, F. X. McCawley and C. Wyche,J. Electrochem. Soc. 116 (1969) 1227.

    Google Scholar 

  108. W. Gullett and F. X. McCawley, US Patent 2933 439 (1960).

    Google Scholar 

  109. L. V. Godulyanet al., Zashch Met. 12 (1976) 476.

    Google Scholar 

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This review was reproduced from the Proceedings of the International Conference on Advances in Surface Coatings Technology, published by the Welding Institute.

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Sethi, R.S. Electrocoating from molten salts. J Appl Electrochem 9, 411–426 (1979). https://doi.org/10.1007/BF00617552

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