Abstract
The electrodeposition of lead onto a glassy carbon electrode from 0·1m HCl solution has been studied mainly by potential step techniques. The early stages of metal deposition are shown to be controlled by a three-dimensional nucleation followed by hemispherical growth. The deposit morphology has been confirmed by scanning electron microscopy (SEM). Results obtained by linear sweep voltammetry are also reported and qualitatively interpreted according to the above-mentioned nucleation mechanism.
Similar content being viewed by others
References
T. M. Florence,J. Electroanalyt. Chem. 35 (1972) 237.
P. Petak and F. Vydra,Analyt. Chim. Acta. 65 (1973) 171.
P. Valenta, L. Mart and H. Rutzel,J. Electroanalyt. Chem. 82 (1977) 327.
G. Torsi,Annali di Chimica 67 (1977) 557.
D. J. Astley, J. A. Harrison and H. R. Tirsk,Trans. Faraday Soc. 64 (1968) 192.
R. Kaischew, A. Scheludko and G. Blinakov,Ber. Bulg. Akad. Wiss. Physik Ser. 1 (1950) 137.
A. Scheludko and M. Todorova,ibid 3 (1952) 61.
R. Kaischew and B. Mutaftschiew,Electrochim. Acta 10 (1965) 643.
D. J. Astley, J. A. Harrison and H. R. Thirsk,J. Electroanalyt. Chem. 19 (1968) 325.
G. W. Tindall and S. Bruchenstein,Analyt. Chem. 40 (1968) 1051.
W. J. Lorenz, I. Moumtzis and E. Schimdt,J. Electroanalyt. Chem. 37 (1971) 121.
G. J. Hills, D. J. Schriffrin and J. Thompson,J. Electrochem. Soc. 120 (1973) 157.
Idem, Electrochim. Acta 19 (1974) 657.
Idem, ibid 19 (1974) 671.
P. Rolland and G. Mamantov,J. Electrochem. Soc. 9 (1976) 1299.
M. Gusteri, V. Bartocci, R. Marassi, F. Pucciarelli and P. Cescon,Annali di Chimica 66 (1976) 501.
M. Fleischmann and H. R. Thirsk, ‘Advances in electrochemistry and electrochemical engineering’ (edited by P. Delay and C. W. Tobias) Vol. 3, Interscience, New York (1963).
J. W. Gibbs, ‘Collected Works’, Longman's Green and Co., London (1928).
O. Volmer.Z. Phys. Chem. 119 (1926) 277.
T. Erdey-Gruz and M. Volmer,Z. Phys. Chem. Abt. A 157 (1931) 165, 182.
R. M. Garrels and F. T. Gucher,Chem. Rev. 44 (1949) 117.
P. Delahay, ‘New instrumental methods in electrochemistry’ Interscience, New York (1954).
W. L. Miller and A. R. Gordon,J. Phys. Chem. 35 (1931) 2785.
G. Mamantov, D. L. Manning and J. M. Dale,J. Electroanalyt. Chem. 9 (1965) 253.
T. Berzin and P. Delahay,J. Amer. Chem. Soc. 75 (1953) 555.
A. Scheludko and M. Todorova,Ber. Bulg. Akad. Wiss. Physik Ser. 3 (1952) 61.
S. Toshev and I. Markov,Ber. Bunsenges. Phys. Chem. 73 (1969) 184.
R. Kaishev, S. Toshev and I. Markov,Bulg. Akad. Sci. Comm. Chem. Dept. 11 (1969) 463.
R. Kaishev and B. Mutaftschiew,Bull. Inst. Phys. Chem. (Sofia) 4 (1954) 105.
Idem, ibid 5 (1955) 77.
R. Kaishev, A. Sheludko and G. Bliznakov,ibid 1 (1950) 137.
A. Sheludko and G. Bliznakov,ibid 2 (1951) 227.
M. Fleischmann, H. R. Thirsk and I. Tordesillas,Trans. Faraday Soc. 58 (1962) 1865.
G. A. Gunawardena, G. J. Hills and I. Montenegro,Electrochim. Acta 23 (1978) 693.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Palmisano, F., Desimoni, E., Sabbatini, L. et al. Nucleation phenomena in the electrodeposition of lead onto glassy carbon electrodes. J Appl Electrochem 9, 517–525 (1979). https://doi.org/10.1007/BF00617564
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00617564