Summary
FeIII reacts with mercaptocarboxylic acids (HORSH), such as 2-mercaptoethanoic acid, 2-mercaptopropanoic acid, 2-mercapto-1,4-butanedioic acid and penicillamine (2-amino3-methyl-3-mercaptobutanoic acid) to give, in perchloric acid medium, 1∶1 complexes, Fe3++HORSH⇄Fe(OSR)++ 2H+. These complexes then undergo redox decomposition to give a disulphide dimer: 2Fe(OSR)++2H+⇄2Fe2++ HOR-S- S- ROH. The present study reports equilibrium data on the stability of the intermediate complexes, and kinetic data for the fast complex formation, as well as for the slower redox decomposition.
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References
D. Leussing, J. P. Mislan and R. J. Goll,J. Am. Chem. Soc., 84, 1070 (1960).
D. Leussing and L. Newman,J. Am. Chem. Soc., 78, 552 (1955).
H. Lamfrom and S. O. Nielsen,J. Am. Chem. Soc., 79, 1966 (1956).
A. Mc Auley and K. J. Ellis,J. Chem. Soc. (A), 1533 (1973).
A. Mc Auley and G. Lappin,J. Chem. Soc., Dalton Trans., 1560 (1975).
A. Mc Auley, G. Lappin and K. J. Ellis,J. Chem. Soc., Dalton Trans., 1930 (1975).
W. H. Orme-Johnson, inInorganic Biochemistry, G. L. Eichhorn Ed. Elsevier, Amsterdam (1973), Vol. 2, Ch. 22;
I. K. Adzamli, D. M. Davies, C. S. Stanley and A. G. Sykes,J. Am. Chem. Soc., 103, 5543 (1981).
A. E. Martell and L. G. Sillen,Stability Constants of Metal-Ion Complexes, Special Publications no. 17 (1964) and no. 25 (1971), The Chemical Society, London; T. Siddal and W. C. Vosburgh,J. Am. Chem. Soc. 73, 4270 (1951).
M. Grant and R. B. Jordan,Inorg. Chem., 20, 55 (1981).
F. K. Meyer, A. R. Monnerat, K. E. Newman and A. E. Merbach,Inorg. Chem., 21, 774 (1982).
C. H. Langford and J. P. K. Tong,Acc. Chem. Res., 10, 258 (1977).
C. Baiocchi and E. Mentasti,Ann. Chim. (Roma), 71, 631 (1981).
A. Mc Auley and A. Olatunji,J. Chem. Soc., Dalton Trans., 682 (1975).
A. Mc Auley and J. P. Mc Cann,J. Chem. Soc., Dalton Trans., 783 (1975).
L. E. Orgel,Quart. Rev., 8, 422 (1954).
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Baiocchi, C., Mentasti, E. & Arselli, P. Kinetics and mechanisms of complex formation and redox reactions of iron(III) with mercaptocarboxylic ligands in acid perchlorate media. Transition Met Chem 8, 40–45 (1983). https://doi.org/10.1007/BF00618796
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DOI: https://doi.org/10.1007/BF00618796