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Iron(III) complexes of some thiosemicarbazones derived from 2-acetylpyridine, its 6-methyl derivative and itsN-oxide

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Summary

A series of iron(III) complexes of thiosemicarbazones derived from 2-acetylpyridine, 6-methyl-2-acetylpyridine and 2-acetylpyridineN-oxide have been prepared from Fe(ClO4)3 and FeCl3. All of the isolated solids have cations involving two monobasic tridentate ligands, and either perchlorate or tetrachloroferrate(III) anions and are 1∶1 electrolytes. Coordinationvia the pyridine nitrogen (or theN-oxide oxygen), the imine nitrogen and the sulphur atom are confirmed by infrared spectra and x-ray diffraction. The presence of two different iron(III) species is indicated by the electron spin resonance spectra of the tetrachloroferrate(III) solids. E.s.r. along with electronic spectra prove the spin-paired configuration of these cationic iron(III) complexes.

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Author notes

  1. Lewis K. Pannell

    Present address: National Institute of Arthritis, Diabetes, Digestive and Kidney Diseases, National Institutes of Health, 20205, Bethesda, MD, USA

Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West, Patricia M. Ahrweiler & Gözen Ertem

  2. Division of Experimental Therapeutics, Walter Reed Army Institute of Research, 20307, Washington, DC, USA

    John P. Scovill & Daniel L. Klayman

  3. Laboratory for the Structure of Matter, Naval Research Laboratory, 20375, Washington, DC, USA

    Judith L. Flippen-Anderson, Richard Gilardi & Clifford George

  4. Laboratory of Biorganic Chemistry, National Heart, Lung and Blood Institute, National Institutes of Health, 20205, Bethesda, MD, USA

    Lewis K. Pannell

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  1. Douglas X. West
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NATO Fellow, on leave from Istanbul Medical Faculty, Istanbul University.

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West, D.X., Ahrweiler, P.M., Ertem, G. et al. Iron(III) complexes of some thiosemicarbazones derived from 2-acetylpyridine, its 6-methyl derivative and itsN-oxide. Transition Met Chem 10, 264–270 (1985). https://doi.org/10.1007/BF00621084

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  • DOI: https://doi.org/10.1007/BF00621084

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