Skip to main content
SpringerLink
Log in

Methylphenylphosphinate complexes with tri- and tetra-positive metal ions

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

A series of methylphenylphosphinate {mpp; [-O-P-Ph(Me)-O-]−} complexes of the forms M(mpp)3 (M = Al, Ga, In, Sc, Y, Dy, Ti, V, Cr and Fe) and M(mpp)4 (M = Th or U) were made from the appropriate metal chloride and a large excess of MeO(Me)PhP(O) at elevated temperatures. Structures involving linear, ligand-bridged polymeric species are suggested on the basis of the i.r. and magnetic data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. P. Block,Inorg. Macromol. Rev., 1, 115 (1970).

    Google Scholar 

  2. R. Cini, P. Colamarino, P. L. Orioli, L. S. Smith, P. R. Newman, H. D. Gillman and P. Nannelli,Inorg. Chem., 16, 3223 (1977).

    Google Scholar 

  3. P. Colamarino, P. L. Orioli, W. D. Benzinger and H. D. Gillman,Inorg. Chem., 15, 800 (1976).

    Google Scholar 

  4. J. C. Scott, A. F. Garito, A. J. Heeger, P. Nannelli and H. D. Gillman,Phys. Rev., B12, 356 (1975); T. S. Wei, J. C. Scott, A. F. Garito, A. J. Heeger, H. D. Gillman and P. Nannelli,ibid., B12, 5297 (1975).

    Google Scholar 

  5. H. D. Gillman,Inorg. Chem., 13, 1921 (1974); H. D. Gillman and J. L. Eichelberger,ibid., 15, 840 (1976).

    Google Scholar 

  6. F. Giordano, L. Randaccio and A. Ripamonti,Acta Crystallogr., B25, 1057 (1969).

    Google Scholar 

  7. V. Giancotti, F. Giordano and A. Ripamonti,Makromol. Chem., 120, 96 (1968);154, 271 (1972).

    Google Scholar 

  8. A. J. Saraceno, J. P. King and B. P. Block,J. Polym. Sci., B6, 15 (1968).

    Google Scholar 

  9. P. Nannelli, B. P. Block, J. P. King, A. J. Saraceno, O. S. Sprout, Jr., N. G. Peschko and G. H. Dahl,J. Polym. Sci., Polym. Chem. Ed., 11, 269 (1973).

    Google Scholar 

  10. P. Nannelli, H. D. Gillman and B. P. Block,J. Polym. Sci., A-1,9. 3027 (1971);ibid., Polym. Chem. Ed., 13, 2849 (1975).

    Google Scholar 

  11. J. J. Pitts, M. A. Robinson and S. I. Trotz,J. Inorg. Nucl. Chem., 30, 1299 (1968);31, 3685 (1969).

    Google Scholar 

  12. V. V. Korshak, A. M. Polyakova, O. V. Vinogradova, K. N. Anisimov, N. E. Kolobova and M. N. Kotova,Izv. Akad. Nauk SSSR, Ser. Khim., 642 (1968); V. V. Korshak, S. V. Vinogradova and O. V. Vinogradova,Vysokomol. Soedin., 16B, 274 (1974).

  13. J. K. Gillham,J. Appl. Polym. Sci., 16, 917 (1972); L. L. Towle and P. Nannelli,ASLE Trans., 17, 224 (1974).

    Google Scholar 

  14. N. M. Karayannis, C. M. Mikulski and L. L. Pytlewski,Inorg. Chim. Acta Rev., 5, 69 (1971).

    Google Scholar 

  15. C. M. Mikulski, N. M. Karayannis, M. J. Strocko, L. L. Pytlewski and M. M. Labes,Inorg. Chem., 9, 2053 (1970).

    Google Scholar 

  16. N. M. Karayannis, C. M. Mikulski, M. J. Strocko, L. L. Pytlewski and M. M. Labes,Inorg. Chim. Acta, 4, 455 (1970); 5, 357 (1971);Z. anorg. allg. Chem., 384, 267 (1971).

    Google Scholar 

  17. C. M. Mikulski, L. L. Pytlewski and N. M. Karayannis,J. Inorg. Nucl. Chem., 36, 971 (1974); Z.anorg. allg. Chem., 403, 200 (1974).

    Google Scholar 

  18. C. M. Mikulski, T. Tran, L. L. Pytlewski and N. M. Karayannis,J. Inorg. Nucl. Chem., 41, 1671 (1979).

    Google Scholar 

  19. V. Gutmann and K. Fenkart,Monatsh. Chem., 99, 1452 (1968); V. Gutmann and G. Beer,Inorg. Chim. Acta, 3, 87 (1969).

    Google Scholar 

  20. J. J. Kokalas, D. N. Kramer, F. Block and R. Levin,Spectrosc. Lett., 2, 273 (1969).

    Google Scholar 

  21. D. D. Schmidt and J. T. Yoke,Inorg. Chem., 9, 1176 (1970).

    Google Scholar 

  22. C. M. Mikulski, J. Unruh, F. J. Iaconianni, L. L. Pytlewski and N. M. Karayannis,Abstr. 178th National Meetg., Am. Chem. Soc., Washington, D. C., Sept. 9–14, 1979; No. INOR 21.

  23. C. M. Mikulski, J. Unruh, R. Rabin, F. J. Iaconianni, L. L. Pytlewski and N. M. Karayannis,Inorg. Chim. Acta, 44, L77 (1980).

    Google Scholar 

  24. C. M. Mikulski, J. Unruh, L. L. Pytlewski and N. M. Karayannis,Transition Met. Chem., 4, 98 (1979).

    Google Scholar 

  25. G. H. Dahl and B. P. Block,Inorg. Chem., 6, 1439 (1967).

    Google Scholar 

  26. L. C. Thomas and R. A. Chittenden,Spectrochim. Acta, 20, 467, 489 (1964);21, 1905 (1965);26A, 781 (1970).

    Google Scholar 

  27. M. I. Kabachnik,Dokl. Akad. Nauk SSSR, 110, 393 (1956);Z. Chem., 1, 289 (1961).

    Google Scholar 

  28. T. A. Mastryukova and M. I. Kabachnik,J. Org. Chem., 36, 1201 (1971).

    Google Scholar 

  29. J. R. Ferraro, D. F. Peppard and G. W. Mason,Spectrochim. Acta, 19, 811 (1963).

    Google Scholar 

  30. M. I. Kabachnik, T. A. Mastryukova, A. E. Shipov and T. A. Melentyeva,Tetrahedron, 9, 10 (1960).

    Google Scholar 

  31. C. M. Mikulski, L. L. Pytlewski and N. M. Karayannis,Inorg. Chim. Acta, 32, 263 (1979).

    Google Scholar 

  32. W. Byers, A. B. P. Lever and R. V. Parish,Inorg. Chem., 7, 1835 (1968).

    Google Scholar 

  33. B. N. Figgis and J. Lewis,Progress in Inorg. Chem., 6, 37 (1964).

    Google Scholar 

  34. B. Jezowska-Trzebiatowska and K. Bukietynska, inTheory and Structure of Complex Compounds, Macmillan, N.Y., 1964, pp. 311–314; B. Jezowska-Trzebiatowska and J. Drozdzynski,J. Inorg. Nucl. Chem., 31, 727 (1969).

    Google Scholar 

  35. S. L. Lambert, T. R. Felthouse and D. N. Hendrickson,Inorg. Chim. Acta, 29, L223 (1978).

    Google Scholar 

  36. C. Wiedenheft,Inorg. Chem., 8, 1174 (1969).

    Google Scholar 

  37. H. Müller and K. Dehnicke,Z. anorg. allg. Chem., 350, 231 (1967).

    Google Scholar 

  38. C. M. Mikulski, N. M. Karayannis, J. V. Minkiewicz, L. L. Pytlewski and M. M. Labes,Inorg. Chim. Acta, 3, 523 (1969).

    Google Scholar 

  39. N. M. Karayannis, L. L. Pytlewski and M. M. Labes,Inorg. Chim. Acta, 3, 415 (1969); N. M. Karayannis, C. M. Mikulski, M. J. Strocko, L. L. Pytlewski and M. M. Labes,ibid., 8, 91 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and Physics, Beaver College, 19038, Glenside, PA, USA

    Chester M. Mikulski, Joseph Unruh & Richard Rabin

  2. Department of Chemistry, Drexel University, 19104, Philadelphia, PA, USA

    Frank J. Iaconnianni & Louis L. Pytlewski

  3. Amoco Chemicals Corporation, 60540, Naperville, IL, USA

    Nicholas M. Karayannis

Authors
  1. Chester M. Mikulski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Joseph Unruh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Richard Rabin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Frank J. Iaconnianni
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Louis L. Pytlewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Nicholas M. Karayannis
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikulski, C.M., Unruh, J., Rabin, R. et al. Methylphenylphosphinate complexes with tri- and tetra-positive metal ions. Transition Met Chem 6, 79–82 (1981). https://doi.org/10.1007/BF00626110

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00626110

Keywords

Search

Navigation