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The structure of lead silicate glasses determined by vibrational spectroscopy

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Abstract

The polarized Raman spectra and infrared powder absorption spectra for PbO ·xSiO2 glasses, with 0.5⩽x⩽2, were measured and interpreted in terms of the structure of the glasses. Comparison of the spectra of the glasses with the spectra of numerous stable and metastable crystalline phases was also made. It was found that the glasses are composed of a number of silicate species. In glasses for whichx is less than 1, the presence of ionic oxygen (oxygen not bonded to silicon) is confidently inferred from the spectra. A new way of deconvoluting the spectra is also reported.

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Authors and Affiliations

  1. Materials Research Laboratory, The Pennsylvania State University, 16802, University Park, Pennsylvania, USA

    T. Furukawa, S. A. Brawer & W. B. White

Authors
  1. T. Furukawa
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  2. S. A. Brawer
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  3. W. B. White
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Also affiliated with the Department of Geosciences.

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Furukawa, T., Brawer, S.A. & White, W.B. The structure of lead silicate glasses determined by vibrational spectroscopy. J Mater Sci 13, 268–282 (1978). https://doi.org/10.1007/BF00647770

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  • DOI: https://doi.org/10.1007/BF00647770

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