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Thermodynamics of liquid mixtures containing n-alkanes and strongly polar components: VE and C EP of mixtures with either pyridine or piperidine

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Abstract

Excess molar volumes V E and excess molar heat capacities C /E P at constant pressure have been obtained, as a function of mole fraction x1, for several binary liquid mixtures belonging either to series I: pyridine+n-alkane (ClH2l+2), with l=7, 10, 14, 16, or series II: piperidine+n-alkane, with l=7, 8, 10, 12, 14. The instruments used were a vibrating-tube densimeter and a Picker flow microcalorimeter, respectively. VE of pyridine+n-heptane shows a S-shaped composition dependence with a small negative part in the region rich in pyridine (x1>0.90). All the other systems show positive VE only. The excess volumes increase with increasing chain length l of the n-alkane. The excess molar heat capacities of the mixtures belonging to series II are all negative, except for a small positive part for piperidine+n-heptane in the region rich in piperidine (x1>0.87). The C /E P at the respective minima, C /E P (x1,min ), become more negative with increasing l, and the x1,min values range from about 0.26 (l=7) to 0.39 (l=14). Most interestingly, mixtures of series I exhibit curves of C /E P against x1 with two minima and one maximum, the so-called W-shape curves.

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References

  1. A. Inglese, E. Wilhelm, and J.-P. E. Grolier,37 th Annual Calorimetry Conference, No. 54 (Snowbird, Utah, 1982).

  2. J.-P. E. Grolier, A. Inglese, and E. Wilhelm,J. Chem. Thermodyn. 16, 67 (1984).

    Google Scholar 

  3. E. Wilhelm,Thermochimica Acta 94, 47 (1985).

    Google Scholar 

  4. E. Wilhelm,Thermochimica Acta 162, 43 (1990).

    Google Scholar 

  5. M. E. Saint-Victor and D. Patterson,Fluid Phase Equil. 35, 237 (1987).

    Google Scholar 

  6. H. Kalali, F. Kohler, and P. Svejda,Monatsh. Chem. 118, 1 (1987).

    Google Scholar 

  7. A. Lainez, G. Roux-Desgranges, J.-P. E. Grolier, and E. Wilhelm,Fluid Phase Equil. 20, 47 (1985).

    Google Scholar 

  8. A. Lainez, E. Wilhelm, G. Roux-Desgranges, and J.-P. E. Grolier,J. Chem. Thermodyn.17, 1153 (1985).

    Google Scholar 

  9. E. Wilhelm, A. Lainez, and J.-P. E. Grolier,Fluid Phase Equil. 49, 233 (1989).

    Google Scholar 

  10. A. Lainez, M. M. Rodrigo, A. H. Roux, J.-P. E. Grolier, and E. Wilhelm,Calorim. Anal. Therm. 16, 153 (1985).

    Google Scholar 

  11. E. Wilhelm, A. H. Roux, G. Roux-Desgranges, M. M. Rodrigo, A. Lainez, and J.-P. E. Grolier,Calorim. Anal. Therm. 17, 12 (1986).

    Google Scholar 

  12. H. Kalali, F. Kohler, and P. Svejda,Fluid Phase Equil. 20, 75 (1985).

    Google Scholar 

  13. E. Wilhelm, A. Lainez, M. M. Rodrigo, A. H. Roux, and J.-P. E. Grolier,Calorim. Anal. Therm. 19, C20.1 (1988).

    Google Scholar 

  14. E. Wilhelm,Calorim. Anal. Therm. 20/21, 413 (1990).

    Google Scholar 

  15. E. A. Guggenheim,Mixtures (Clarendon Press, Oxford, 1952).

    Google Scholar 

  16. R. G. Rubio, M. Cáceres, R. M. Masegosa, L. Andreolli-Ball, M. Costas, and D. Patterson,Ber. Bunsenges. Phys. Chem. 93, 48 (1989).

    Google Scholar 

  17. L. Andreolli-Ball, M. Costas, D. Patterson, R. G. Rubio, M. Cáceres, and R. M. Masegosa,Ber. Bunsenges. Phys. Chem. 93, 882 (1989).

    Google Scholar 

  18. A. B. Bathia and D. E. Thornton,Phys. Rev. B 2, 3004 (1970).

    Google Scholar 

  19. J. S. Rowlinson and F. L. Swinton,Liquids and Liquid Mixtures, 3rd edn., (McGraw-Hill, New York, 1982).

    Google Scholar 

  20. A. J. Treszczanowicz, D. Patterson, G. C. Benson, and T. Kasprzycka-Guttman,Fluid Phase Equil. 50, 235 (1989).

    Google Scholar 

  21. T. Kasprzycka-Guttman and H. Kurcinska,J. Solution Chem. 18, 727 (1989).

    Google Scholar 

  22. R. K. Nigam, P. P. Singh, S. Aggarwal, and S. P. Sharma,Fluid Phase Equil. 16, 25 (1984).

    Google Scholar 

  23. B. Kowalski, A. Boniecka, and A. Orszagh,Pol. J. Chem. 52, 1079 (1978).

    Google Scholar 

  24. M. Woycicka,Pure Appl. Chem. 2, 147 (1961).

    Google Scholar 

  25. T. Kasprzycka-Guttman and H. Wilczura,J. Thermal Anal. 35, 2441 (1989);

    Google Scholar 

  26. —,Thermochimica Acta 158, 1 (1990).

    Google Scholar 

  27. R. K. Nigam and S. Aggarwal,Fluid Phase Equil. 26, 181 (1986).

    Google Scholar 

  28. E. G. Konakbaeva,Int. DATA Ser., Sel. Data Mixtures Ser. A 50, 51 (1985).

    Google Scholar 

  29. H. Wilczura, T. Kasprzycka-Guttman, and S. Randzio,Bull. Pol. Acad. Sci. Chem. 34, 483 (1987).

    Google Scholar 

  30. T. Kasprzycka-Guttman and I. Chojnacka,J. Chem. Thermodyn. 21, 721 (1989).

    Google Scholar 

  31. M.-A. Michou-Saucet, J. Jose, and C. Michou-Saucet,Thermochimica Acta 102, 271 (1986);

    Google Scholar 

  32. M.-A. Michou-Saucet, J. Jose, and C. Michou-Saucet,Int. Data Ser., Sel. Data Mixtures, Ser. A 140–145 (1986).

  33. E. G. Konakbaeva,Int. Data Ser., Sel. Data Mixtures, Ser. A 41 (1985).

  34. A. Ait-Kaci and H. V. Kehiaian,Int. Data Ser., Sel. Data Mixtures, Ser. A 42, 43 (1985).

    Google Scholar 

  35. S. Warycha and J. H. Rytting,J. Solution Chem. 13, 589 (1984).

    Google Scholar 

  36. Z. Maczynska,Int. Data Ser., Sel. Data Mixtures, Ser. A, 104–115 (1980).

  37. J.-P. Herbeuval, M.-L. Gaulard, and P. Boule,J. Chim. Phys. 71, 326 (1974).

    Google Scholar 

  38. R. E. Cornish, R. C. Archibald, E. A. Murphy, and H. M. Evans,Ind. Eng. Chem. 26, 397 (1934).

    Google Scholar 

  39. A. W. Francis,Ind. Eng. Chem. 36, 764 (1944).

    Google Scholar 

  40. A. Kreglewski,Rocz. Chem. 31, 1001 (1957).

    Google Scholar 

  41. E. Brunner,J. Chem. Thermodyn. 19, 823 (1987).

    Google Scholar 

  42. IUPAC,Pure Appl. Chem. 58, 1677 (1986).

    Google Scholar 

  43. J.-P. E. Grolier, E. Wilhelm, and M. H. Hamedi,Ber. Bunsenges. Phys. Chem. 82, 1282 (1978).

    Google Scholar 

  44. G. S. Kell,J. Chem. Eng. Data 20, 97 (1975).

    Google Scholar 

  45. J. L. Fortier, G. C. Benson, and P. Picker,J. Chem. Thermodyn. 8, 289 (1976).

    Google Scholar 

  46. J. L. Fortier and G. C. Benson,J. Chem. Thermodyn. 8, 411 (1976).

    Google Scholar 

  47. E. Wilhelm, J.-P. E. Grolier, and M. H. Karbalai Ghassemi,Ber. Bunsenges. Phys. Chem. 81, 925 (1977).

    Google Scholar 

  48. J. A. Riddick and W. B. Bunger,Organic Solvents, 3rd edn., (Wiley, New York, 1970).

    Google Scholar 

  49. V. T. Lam, P. Picker, D. Patterson, and P. Tancrede,J. Chem. Soc. Faraday Trans. II 70, 1465 (1974).

    Google Scholar 

  50. J. Weclawski,Fluid Phase Equil. 12, 155 (1983).

    Google Scholar 

  51. J. Timmermans,Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, 1965).

    Google Scholar 

  52. E. A. Moelwyn-Hughes and P. L. Thorpe,Proc. Roy. Soc. London (A) 278, 574 (1964).

    Google Scholar 

  53. K. Nakanishi, H. Wada, and H. Touhara,J. Chem. Thermodyn. 7, 1125 (1975).

    Google Scholar 

  54. Selected Values of Physical, and Thermodynamic Properties of Hydrocarbons, and Related Compounds, American Petroleum Institute, Research Project 44, (Carnegie Press, Pittsburgh, Pa, 1953).

  55. TRC Thermodynamic Tables: Hydrocarbons, 1986. Data sheets d-1011, andd-1014 (June 30, 1973) Texas A&M University, College Station Texas.

  56. A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermodyn. 12, 173 (1980).

    Google Scholar 

  57. D. L. Camin and F. D. Rossini,J. Phys. Chem. 59, 1173 (1955).

    Google Scholar 

  58. TRC Thermodynamic Tables: Non Hydrocarbons, 1986, p. 9410. Texas A&M University, College Station Texas.

  59. J. F. Messerly, S. S. Todd, H. L. Finke, W. D. Good, and B. E. Gammon,J. Chem. Thermodyn. 20, 209 (1988).

    Google Scholar 

  60. J.-P. E. Grolier, A. Inglese, A. H. Roux, and E. Wilhelm,Ber. Bunsenges. Phys. Chem. 85, 768 (1981).

    Google Scholar 

  61. J. F. Messerly, G. B. Guthrie, S. S. Todd, and H. L. Finke,J. Chem. Eng. Data 12, 338 (1967).

    Google Scholar 

  62. A. H. Roux, J.-P. E. Grolier, A. Inglese, and E. Wilhelm,Ber. Bunsenges. Phys. Chem. 88, 986 (1984).

    Google Scholar 

  63. J.-P. E. Grolier and G. C. Benson,Can. J. Chem. 62, 949 (1984).

    Google Scholar 

  64. D. Ambrose,NPL Report Chem. 107 (1980).

  65. R. C. Reid, J. P. Prausnitz, and T. K. Sherwood,The Properties of Gases and Liquids, 3rd edn., (McGraw, New York, 1977).

    Google Scholar 

  66. R. D. Nelson, Jr., D. R. Lide, Jr., and A. A. Maryott,Selected Values of Electric Dipole Moments for Molecules in the Gas Phase,NSRDS-NBS 10 (National Bureau of Standards, Washington, D. C., 1967).

    Google Scholar 

  67. V. M. Rao and R. Kewley,Can. J. Chem. 50, 955 (1972).

    Google Scholar 

  68. G. O. Sorensen, L. Mahler, and N. Rastrup-Andersen,J. Molecular Struct. 20, 119 (1974).

    Google Scholar 

  69. J. E. Parkin, P. J. Buckley, and C. C. Costain,J. Molecular Spectr. 89, 465 (1981).

    Google Scholar 

  70. R. N. Joarder and M. Silbert,Chem. Phys. 95, 357 (1985).

    Google Scholar 

  71. S. Malanowski, R. Patz, M. T. Rätzsch, and C. Wohlfarth,Fluid Phase Equil. 3, 291 (1979).

    Google Scholar 

  72. P. P. Singh and S. P. Sharma,Thermochimica Acta 88, 467 (1985).

    Google Scholar 

  73. W. Brzostowski,J. Chim. Phys. 66, 314 (1969).

    Google Scholar 

  74. R. Smets and P. Huyskens,Bull. Soc. Chim. France 173 (1978).

  75. W. Woycicki and K. W. Sadowska,Bull. Acad. Pol. Sci., Ser. Sci. Chim. 16, 365 (1968);

    Google Scholar 

  76. W. Woycicki and K. W. Sadowska,Int. Data Ser., Sel. Data Mixtures, Ser. A, 33 (1975).

  77. A. Lainez, M. M. Rodrigo, J.-P. E. Grolier, and E. Wilhelm, unpublished results.

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Authors and Affiliations

  1. Departamento de Química Física, Facultad de C.C. Químicas, Universidad Complutense, 28040, Madrid, Spain

    A. Lainez

  2. Departamento de Química Física, Universidad de Alcalá de Henares, 28871, Madrid, Spain

    M. M. Rodrigo

  3. Institut für Physikalische Chemie, Universität Wien, Währingerstr. 42, A-1090, Wien, Austria

    Emmerich Wilhelm

  4. Laboratoire de Thermodynamique et Cinétique Chimique, Université Blaise Pascal, F-63177, Aubière, France

    J. -P. E. Grolier

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  1. A. Lainez
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  4. J. -P. E. Grolier
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Dedicated to Professor A. Néckel on the occasion of his 65th birthday. Communicated in part at the XVIIèmes Journées de Calorimétrie, d'Analyse Thermique et de Thermodynamique Chimique, Ferrara, Italy, 27–30 October, 1986.

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Lainez, A., Rodrigo, M.M., Wilhelm, E. et al. Thermodynamics of liquid mixtures containing n-alkanes and strongly polar components: VE and C EP of mixtures with either pyridine or piperidine. J Solution Chem 21, 49–65 (1992). https://doi.org/10.1007/BF00648980

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