Skip to main content
SpringerLink
Log in

Prediction of excess enthalpies for ternary aqueous solutions of nonelectrolytes

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The excess enthalpiesH E xy of ternary aqueous solutions of nonelectrolytes are used to test the possibility of making predictions for ternary solutions from the properties of the binary solutions only. Two methods are proposed: one is based on the empirical rule (h xx ·h yy )1/2=h xy . Another leads to the numerical prediction of the overallH Exy . Both are successful for most of the pairs of solutes for whichH Ex ,H Ey >0.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. G. McMillan, Jr., and J. E. Mayer,J. Chem. Phys. 13, 276 (1945).

    Article  CAS  Google Scholar 

  2. J. J. Kozak, W. S. Knight, and W. Kauzmann,J. Chem. Phys. 48, 675 (1968).

    Article  CAS  Google Scholar 

  3. H. L. Friedman and C. V. Krishnan,J. Solution Chem. 2, 119 (1973).

    Article  CAS  Google Scholar 

  4. T. H. Lilley and R. P. Scott,J. Chem. Soc. Faraday Trans. 1 72, 184 (1976).

    Article  CAS  Google Scholar 

  5. F. Franks, M. Pedley, and D. S. Reid,J. Chem. Soc. Faraday Trans. 1 72, 359 (1976).

    Article  CAS  Google Scholar 

  6. J. E. Desnoyers, G. Perron, L. Avédikian, and J-P. Morel,J. Solution Chem. 5, 631 (1976).

    Article  CAS  Google Scholar 

  7. J. J. Savage and R. H. Wood,J. Solution Chem. 5, 733 (1976).

    Article  CAS  Google Scholar 

  8. G. Barone, G. Castronuovo, V. Crescenzi, V. Elia, and E. Rizzo,J. Solution Chem. 7, 179 (1978).

    CAS  Google Scholar 

  9. G. Barone, G. Castronuovo, V. Elia, and A. Menna,J. Solution Chem. 8, 157 (1979).

    Article  CAS  Google Scholar 

  10. S. Ablett, M. D. Barratt, F. Franks, M. D. Pedley, and D. S. Reid, inL'eau et les systems biologiques, A. Alfsen and A. J. Berteaud, eds (Editions du CNRS, Paris, 1976), p. 105.

    Google Scholar 

  11. F. Franks,Philos. Trans. R. Soc. London B 278, 33 (1977).

    CAS  Google Scholar 

  12. A. H. Clark, F. Franks, M. D. Pedley, and D. S. Reid,J. Chem. Soc. Faraday Trans. 1 73, 290 (1977).

    Article  CAS  Google Scholar 

  13. F. Franks, inBiochemical Thermodynamics, M. N. Jones, ed. (Elsevier, Amsterdam, 1979), Chap. 2.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Istituto Chimico, University of Naples, 80134, Naples, Italy

    Guido Barone, Giuseppina Castronuovo & Vittorio Elia

Authors
  1. Guido Barone
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Giuseppina Castronuovo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Vittorio Elia
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Barone, G., Castronuovo, G. & Elia, V. Prediction of excess enthalpies for ternary aqueous solutions of nonelectrolytes. J Solution Chem 9, 607–615 (1980). https://doi.org/10.1007/BF00649034

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00649034

Key words

Search

Navigation