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Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

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Summary

Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M]2,[ACP] and [Ce(IV)]−1. Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

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Authors and Affiliations

  1. Department of Chemistry, Istanbul Technical University, Maslak, TR-80626, Istanbul, Turkey

    Ümit Tunca, I. Ersin Serhatli & Yusuf Yağci

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  1. Ümit Tunca
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  2. I. Ersin Serhatli
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  3. Yusuf Yağci
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Tunca, Ü., Ersin Serhatli, I. & Yağci, Y. Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol). Polymer Bulletin 22, 483–488 (1989). https://doi.org/10.1007/BF00718923

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  • DOI: https://doi.org/10.1007/BF00718923

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