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Polymer modified mixed metal alkoxide-metal acetyl acetonate sol-gel materials

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Summary

Metal acetyl acetonates of aluminum, zirconium and zinc have been successfully incorporated into poly (tetramethylene oxide) modified TEOS based materials using sol-gel chemistry. Incorporation of these metal acetyl acetonates required modification of the reaction scheme developed earlier to incorporate titanium(IV) isopropoxide. Gelation rates and the physical properties of the subsequent gelled materials varied as a function of the metal acetyl acetonate used.

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Author notes

  1. Raymond H. Glaser

    Present address: Mt. Vernon Technology Department, The General Electric Company, Highway 69 South, 47620, Mt. Vernon, IN, USA

Authors and Affiliations

  1. Department of Chemical Engineering, Polymer Materials Interfaces Laboratory, Virginia Polytechnic Institute and State University, 24061-6496, Blacksburg, VA, USA

    Raymond H. Glaser & Garth L. Wilkes

Authors
  1. Raymond H. Glaser
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  2. Garth L. Wilkes
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Glaser, R.H., Wilkes, G.L. Polymer modified mixed metal alkoxide-metal acetyl acetonate sol-gel materials. Polymer Bulletin 22, 527–532 (1989). https://doi.org/10.1007/BF00718929

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  • DOI: https://doi.org/10.1007/BF00718929

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