Conclusion
The data obtained on the behavior of the CsCl type lattice containing complex octahedral anions allow us to conclude that their dynamic behavior is mainly similar to the behavior of analogous crystals with the fluorite structure. The connection between phase transitions in such systems and the rotational dynamics of the complex anions confirms the generality of the nature of rotational phase transitions in complex compounds [7].
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Deceased.
Institute of Inorganic Chemistry, Siberian Branch Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 28, No. 2, pp. 42–49, March–April, 1987.
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Gabuda, S.P., Goncharuk, V.K., Zil'berman, B.D. et al. Quadrupole effects and NMR relaxation in KVF6 . J Struct Chem 28, 200–206 (1987). https://doi.org/10.1007/BF00751662
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DOI: https://doi.org/10.1007/BF00751662