Abstract
Pure unpromoted Mn3O4 appears to be a very suitable catalyst for the selective reduction of nitrobenzene to nitrosobenzene; the oxygen vacancies required to split off oxygen atoms can be created both by the phenyl group of nitrobenzene itself and by an additional reducing agent like e.g. methane.
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Favre, T.L.F., Seijsener, P.J., Kooyman, P.J. et al. Selective reduction of nitrobenzene to nitrosobenzene on oxidic catalysts. Catal Lett 1, 457–460 (1988). https://doi.org/10.1007/BF00766206
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DOI: https://doi.org/10.1007/BF00766206