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[4+2] Cycloadditionen an Chinone Eine theoretische Untersuchung zur Regioselektivität

[4+2] Cycloadditions to quinones. A theoretical investigation on the regioselectivity

  • Organische Chemie Und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Intermolecular perturbation theory has been used to treat the regioselectivity observed with [4+2] cycloadditions to quinones. Using 15 model reactions which are key steps in the synthesis of a number of biologically important natural as well as synthetic products the usefulness of this theoretical method for predicting the regioselectivity of cycloadditions is clearly demonstrated. Furthermore the various contributions to the total interaction energy are discussed in some detail.

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  1. Institut für Organische Chemie, Abteilung für Spektroskopie und Theoretische Organische Chemie, Universität Graz, A-8010, Graz, Österreich

    Walter Fabian

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  1. Walter Fabian
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Fabian, W. [4+2] Cycloadditionen an Chinone Eine theoretische Untersuchung zur Regioselektivität. Monatsh Chem 117, 1057–1072 (1986). https://doi.org/10.1007/BF00811276

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  • DOI: https://doi.org/10.1007/BF00811276

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