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β-Keto phosphonic esters

Communication 11. Action of diazomethane on diethyl acetyl- and benzoylphosphonates

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the reaction of diazomethane with diethyl acetylphosphonate diethyl 1,2-epoxy-1-methylethylphosphonate and a little diethyl acetonylphosphonate were obtained.

  2. 2.

    Diethyl 1,2-epoxy-1-methylethylphosphonate was obtained also by the oxidation of diethyl isopropenyl-phosphonate with peroxyacetic acid.

  3. 3.

    By the reaction of diazomethane with diethyl benzoylphosphonate diethyl phenacylphosphonate was obtained.

  4. 4.

    The addition of phosphorus pentachloride to α-ethoxystyrene gave β-ethoxystyrylphosphonic dichloride, which was converted into diethyl β-ethoxystyrylphosphonate. Hydrolysis of the latter gave diethyl phenacylphosphonate.

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, V. I. Ul'yanov-Lenin Kazan' State University, USSR

    B. A. Arbuzov, V. S. Vinogradova, N. A. Polezhaeva & A. K. Shamsutdinova

Authors
  1. B. A. Arbuzov
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  2. V. S. Vinogradova
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  3. N. A. Polezhaeva
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  4. A. K. Shamsutdinova
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Arbuzov, B.A., Vinogradova, V.S., Polezhaeva, N.A. et al. β-Keto phosphonic esters. Russ Chem Bull 12, 604–610 (1963). https://doi.org/10.1007/BF00843950

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  • DOI: https://doi.org/10.1007/BF00843950

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