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Study of electrophilic substitution reactions at the olefinic carbon atom Communication 4. Kinetics and stereochemistry of the reaction of cis-and trans-β-chlorovinyl-mercury chlorides with iodine in carbon tetrachloride and benzene

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the reaction of trans-β-chlorovinylmercury chloride with iodine was studied in nonpolar solvents-carbon tetrachlorine and benzene.

  2. 2.

    In nonpolar solvents the reaction proceeds without conservation of the geometrical configuration. Each of the isomers ofβ-chlorovinylmercury chloride gives the same equimolar mixture of trans- and cis-1,2-chloroiodoethylenes.

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Literature cited

  1. I. P. Beletskaya, O. A. Reutov, and V. I. Karpov, Izv. AN SSSR. Otd. Khim N.,1961, 1961, 2125, 2129.

  2. I. P. Beletskaya, O. A. Reutov, and T. P. Gur'yanova, Izv. AN SSSR. Otd. Khim. N.,1961, 2178.

  3. I. P. Beletskaya, O. A. Reutov, and T. A. Azizyan, Izv. AN SSSR. Otd. Khim. N.,1962, 223.

  4. V. Walle, Bull. Acad. Poy. Belg. (5), 360 (1915); Chem. Zbl.1926, I, 1871.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, V. I. Karpov & O. A. Reutov

Authors
  1. I. P. Beletskaya
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  2. V. I. Karpov
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  3. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 963–966, June, 1966.

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Beletskaya, I.P., Karpov, V.I. & Reutov, O.A. Study of electrophilic substitution reactions at the olefinic carbon atom Communication 4. Kinetics and stereochemistry of the reaction of cis-and trans-β-chlorovinyl-mercury chlorides with iodine in carbon tetrachloride and benzene. Russ Chem Bull 15, 921–923 (1966). https://doi.org/10.1007/BF00846040

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  • DOI: https://doi.org/10.1007/BF00846040

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