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Stereochemistry of the reaction of the cis-trans isomers of styrylmercury bromide with bromine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The stereochemistry of the reaction of the isomeric ω-styrylmercury bromides with bromine in various solvents was studied.

  2. 2.

    In dimethyl sulfoxide (SEl mechanism) the reaction goes with a retention of the geometric configuration, while in C6H6 and CCl4 (sR mechanism) the configuration is not retained.

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Literature cited

  1. I. P. Beletskaya, O. A. Reutov, and V. I. Karpov, Izv. AN SSSR, Otd. Khim. Nauk,1961, 1961.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, V. I. Karpov & O. A. Reutov

Authors
  1. I. P. Beletskaya
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  2. V. I. Karpov
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  3. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1707–1709, September, 1964

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Beletskaya, I.P., Karpov, V.I. & Reutov, O.A. Stereochemistry of the reaction of the cis-trans isomers of styrylmercury bromide with bromine. Russ Chem Bull 13, 1615–1617 (1964). https://doi.org/10.1007/BF00846306

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  • DOI: https://doi.org/10.1007/BF00846306

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