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Copolymerization of vinyltrimethylsilane with styrene in the presence of butyllithium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The anionic copolymerization of vinyltrimethylsilane with styrene was conducted in the presence of butyllithium, and copolymers were obtained from the indicated monomers.

  2. 2.

    The relative activity of the pair styrene-vinyltrimethylsilane in the process of anionic copolymerization was investigated. The constant of the relative activity of styrene is 5.7±0.03, while that of vinyltrimethylsilane is 0.06±0.01.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR

    V. G. Filippova, N. S. Nametkin & S. G. Durgar'yan

Authors
  1. V. G. Filippova
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  2. N. S. Nametkin
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  3. S. G. Durgar'yan
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Additional information

The article is published on the basis of a resolution of the Conference of Editors in Chief of the Journals of the Academy of Sciences of the USSR, of July 12, 1962 as the dissertation work of V. G. Filippova.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 1727–1731, October, 1966.

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Filippova, V.G., Nametkin, N.S. & Durgar'yan, S.G. Copolymerization of vinyltrimethylsilane with styrene in the presence of butyllithium. Russ Chem Bull 15, 1670–1673 (1966). https://doi.org/10.1007/BF00848700

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  • DOI: https://doi.org/10.1007/BF00848700

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