Conclusions
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1.
The interaction of perfluoroisobutylene oxide with ammonia and dimethylamine leads to dimethylamides ofα-aminoperfluoroisobutyric acids.
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2.
The isomerization of perfluoroisobutylene oxide is a convenient comparative method for the production of perfluoroisobutyryl fluorides.
Literature cited
I. L. Knunyants, V. V. Shokina, and I. V. Galakhov, Khimiya Geterotsikl. soed., No. 6 (1966).
Yu. A. Cheburkov, Yu. E. Aronov, É. I. Fedin, P. V. Petrovskii, and I. L. Knunyants, Dokl. AN SSSR,169, 128 (1966).
F. S. Fawcett, C. W. Tullok, and D. Koffman, J. Amer. Chem. Soc.,84, 4275 (1962).
I. L. Knunyants, Yu. A. Cheburkov, and M. D. Bargamova, Izv. AN SSSR, Ser. khim.,1963, 1393.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 1831–1833, October 1966
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Knunyants, I.L., Shokina, V.V., Tyuleneva, V.V. et al. Derivatives of perfluoroisobutyric acid. Russ Chem Bull 15, 1764–1766 (1966). https://doi.org/10.1007/BF00848722
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DOI: https://doi.org/10.1007/BF00848722