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Study of the mechanism of the para and ortho rearrangements of substituted azoxy compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The influence of substituents on the mechanism of the rearrangement of azoxy compounds into para-and ortho-hydroxyazo compounds has been studied.

  2. 2.

    Regardless of the structure of the azoxy compounds, their para-rearrangement always takes place by an intermolecular mechanism.

  3. 3.

    Two types of ortho-rearrangement of azcxy compounds have been found: intermolecular, which is the most usual, and intramolecular, taking place with the participation of the external medium.

  4. 4.

    The mechanism of the para-and ortho-rearrangements of azoxy compounds has been discussed.

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Literature cited

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Authors and Affiliations

  1. Institute for the Chemistry of Natural Compounds, Academy of Sciences of the USSR, USSR

    M. M. Shemyakin, Ts. E. Agadzhanyan, V. I. Maimind & R. V. Kudryavtsev

Authors
  1. M. M. Shemyakin
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  2. Ts. E. Agadzhanyan
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  3. V. I. Maimind
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  4. R. V. Kudryavtsev
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Shemyakin, M.M., Agadzhanyan, T.E., Maimind, V.I. et al. Study of the mechanism of the para and ortho rearrangements of substituted azoxy compounds. Russ Chem Bull 12, 1216–1219 (1963). https://doi.org/10.1007/BF00849690

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  • DOI: https://doi.org/10.1007/BF00849690

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