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Synthesis of mono- and di-acetylenic hydrocarbons containing quaternary carbon atoms

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the alkylation of t-alkyl chlorides with vinyl chloride in presence of metal halides the following dichloroalkanes were synthesized for the first time: 1,1-dichloro-3,3,4-trimethylpentane, 1,1-dichloro-3,3,4,4-trimethylpentane, 1,1-dichloro-3,3,5,5-tetramethylhexane.

  2. 2.

    By the dehydrochlorination of 1,1-dichloralkanes over KOH in diethylene glycol monoacetylenic hydrocarbons containing quaternary carbon atoms were prepared for the first time.

  3. 3.

    The following diacetylenic hydrocarbons were prepared for the first time by oxidative dimerization: 3,3,8,8-tetramethyl-4,6-decadiyne, 2,3,3,8,8,9-hexamethyl-4,6-decadiyne, 2,2,3,3,8,8,9,9-octamethyl-4,6-decadiyne, and 2,2,4,4,9,9,11,11-octamethyl-5,7-dodecadiyne.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    A. P. Meshcheryakov & L. V. Petrova

Authors
  1. A. P. Meshcheryakov
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  2. L. V. Petrova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8 pp. 1488–1497, August, 1964

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Meshcheryakov, A.P., Petrova, L.V. Synthesis of mono- and di-acetylenic hydrocarbons containing quaternary carbon atoms. Russ Chem Bull 13, 1391–1398 (1964). https://doi.org/10.1007/BF00850341

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  • DOI: https://doi.org/10.1007/BF00850341

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