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Study of the mechanism of the reactions of organomercury compounds by the method of chemically induced dynamic polarization of the nuclei

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The polarization of the protons of PhCH2CPh3, the product of the “Wurtz reaction” between trityl bromide and XC6H4CH4HgBr, was detected. The one-electron mechanism of the reaction was proved.

  2. 2.

    The polarization of the protons of Ph3CBr during their formation of the complex with XC6H4CH2 · HgBr was detected.

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Literature cited

  1. I. P. Beletskaya, V. B. Vol'eva, V. B. Golubev, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 1197 (1969).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow

    I. P. Beletskaya, V. B. Vol'eva, S. V. Rykov, A. L. Buchachenko & A. V. Kessenikh

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    I. P. Beletskaya, V. B. Vol'eva, S. V. Rykov, A. L. Buchachenko & A. V. Kessenikh

  3. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    I. P. Beletskaya, V. B. Vol'eva, S. V. Rykov, A. L. Buchachenko & A. V. Kessenikh

Authors
  1. I. P. Beletskaya
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  2. V. B. Vol'eva
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  3. S. V. Rykov
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  4. A. L. Buchachenko
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  5. A. V. Kessenikh
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 454–456, February, 1971.

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Beletskaya, I.P., Vol'eva, V.B., Rykov, S.V. et al. Study of the mechanism of the reactions of organomercury compounds by the method of chemically induced dynamic polarization of the nuclei. Russ Chem Bull 20, 397–399 (1971). https://doi.org/10.1007/BF00869060

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  • DOI: https://doi.org/10.1007/BF00869060

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