Conclusions
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1.
The polarization of the protons of PhCH2CPh3, the product of the “Wurtz reaction” between trityl bromide and XC6H4CH4HgBr, was detected. The one-electron mechanism of the reaction was proved.
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2.
The polarization of the protons of Ph3CBr during their formation of the complex with XC6H4CH2 · HgBr was detected.
Literature cited
I. P. Beletskaya, V. B. Vol'eva, V. B. Golubev, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 1197 (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 454–456, February, 1971.
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Beletskaya, I.P., Vol'eva, V.B., Rykov, S.V. et al. Study of the mechanism of the reactions of organomercury compounds by the method of chemically induced dynamic polarization of the nuclei. Russ Chem Bull 20, 397–399 (1971). https://doi.org/10.1007/BF00869060
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DOI: https://doi.org/10.1007/BF00869060