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Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator

  • Optics and Spectroscopy
  • Published:
Soviet Physics Journal Aims and scope

Abstract

An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H2O on the “bending” quantum number v2 on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H2O on v2 describes the experimental behavior of these constants well.

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Literature cited

  1. C. Camy-Peyret and J. M. Flaud, Mol. Phys.,32, No. 2, 523 (1976).

    Google Scholar 

  2. J. M. Flaud and C. Camy-Peyret, Mol. Phys.,26, No. 4, 811 (1973).

    Google Scholar 

  3. C. Camy-Peyret and J. M. Flaud, Spectrochem. Acta,29A, 1711 (1973).

    Google Scholar 

  4. C. Camy-Peyret and J. M. Flaud, J. Phys. Lett.,41, L23 (1980).

    Google Scholar 

  5. H. H. Nielsen, Handb. Phys., 37/1, 173 (1959).

    Google Scholar 

  6. V. I. Starikov and Vl. G. Tyuterev, Opt. Spektrosk.,52, No. 2, 286 (1981).

    Google Scholar 

  7. V. I. Starikov and Vl. G. Tyuterev, Preprint No. 29, Tomsk (1979).

  8. V. P. Bakhrakh and S. I. Vetchinkin, Opt. Spektrosk.,32, 28 (1972).

    Google Scholar 

  9. J. T. Hougen, P. R. Bunker, and J. W. G. Johns, J. Mol. Spectrosc.,34, 136 (1970).

    Google Scholar 

  10. D. Kivelson and E. B. Wilson, J. Chem. Phys.,20, 575 (1952).

    Google Scholar 

  11. M. R. Aliev and J. K. G. Watson, J. Mol. Spectrosc.,61, No. 1, 29 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Atmospheric Optics, Siberian Branch, Academy of Sciences of the USSR, USSR

    V. I. Starikov & Vl. G. Tyuterev

Authors
  1. V. I. Starikov
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  2. Vl. G. Tyuterev
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Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 93–96, August, 1982.

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Starikov, V.I., Tyuterev, V.G. Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator. Soviet Physics Journal 25, 762–765 (1982). https://doi.org/10.1007/BF00895258

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  • DOI: https://doi.org/10.1007/BF00895258

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