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Infrarot-und Raman-Spektren von unvollständig und vollständig deuterierten Tetramethyl-Verbindungen (CH3) n M(CD3)4-n der ElementeM=Si, Ge, Sn und Pb

Infrared and raman spectra of partially and fully deuterated tetramethyl Derivatives (CH3)nM(CD3)4-n of the elements M=Si, Ge, Sn and Pb

  • Anorganische und Physikalische Chemie
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Abstract

The infrared andRaman spectra of theM(CH3)4 andM(CD3)4 species,M=Si, Ge, Sn and Pb, have been reinvestigated. The spectra of the mixed tetramethyl compounds (CH3)3 MCD3,M=Si, Ge, Sn and Pb, and of (CH3)2Si(CD3)2 and CH3Si(CD3)3 have been recorded in the gaseous (i.r.) and liquid states (Raman). The proposed assignment is supported by a normal coordinate analysis.

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Author notes

  1. Hans Bürger

    Present address: FB 9-Anorganische Chemie, Gesamthochschule, Gaußstraße 20, D-5600, Wuppertal 1, Bundesrepublik Deutschland

Authors and Affiliations

  1. Institut für Anorganische Chemie, Technische Universität Braunschweig, D-3300, Braunschweig, Bundesrepublik Deutschland

    Siegfried Biedermann & Hans Bürger

  2. Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010, Graz, Österreich

    Karl Hassler & Friedrich Höfler

Authors
  1. Siegfried Biedermann
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  2. Hans Bürger
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  3. Karl Hassler
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  4. Friedrich Höfler
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Biedermann, S., Bürger, H., Hassler, K. et al. Infrarot-und Raman-Spektren von unvollständig und vollständig deuterierten Tetramethyl-Verbindungen (CH3) n M(CD3)4-n der ElementeM=Si, Ge, Sn und Pb. Monatshefte für Chemie 111, 703–714 (1980). https://doi.org/10.1007/BF00903324

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  • DOI: https://doi.org/10.1007/BF00903324

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