Abstract
Fromthe experiemntal fundamental vibrational frequencies of (CH3)4 M, (CD3)4 M and (CH3)3 MCD3,M=Si, Ge, Sn, Pb, and of (CH3)2Si(CD3)2 and CH3Si(CD3)3 a transferable local symmetry type force field for (CH3)4−n M groups has been calculated. Applications involving differentM atoms and numbersn of CH3 groups are presented.
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Biedermann, S., Bürger, H., Hassler, K. et al. Modellrechnungen von Kraftkonstanten der Tetramethyl-Verbindungen (CH3)4−nM(CD3) n ,M=Si, Ge, Sn, Pb. Monatshefte für Chemie 111, 715–725 (1980). https://doi.org/10.1007/BF00903325
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DOI: https://doi.org/10.1007/BF00903325