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Die IR-Spektren einiger Metavanadate mit tetraedrischer Vanadin-Koordination

The I.R. spectra of some metavanadates with tetrahedral vanadium coordination

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The infrared spectra of the isostructuralMVO3 compounds (M=K, Rb, Cs, Tl, NH4), consisting in an array of infinite tetrahedral chains, are reported and discussed with the aid of a simplified factor group analysis. In the case of NH4VO3 also the laser-Raman spectrum was recorded and analyzed. Force constants, mean amplitudes of vibration and other bond properties for the terminal VO2 groups, as well as for the VOV chain units are estimated.

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Authors and Affiliations

  1. Cátedra de Quimica Inorgánica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calle 47 esq. 115, ARG-1900, La Plata, Argentinien

    Irma L. Botto,  Enrique J. Baran & Pedro J. Aymonino

Authors
  1. Irma L. Botto
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  2. Enrique J. Baran
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  3. Pedro J. Aymonino
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Additional information

17. Mitteilung der Reihe „Orthovanadate und verwandte Verbindungen”. 16. Mitt.:I. L. Botto undE. J. Baran, Z. anorg. allgem. Chem., im Druck; 15. Mitt.:E. J. Baran undI. L. Botto, Mh. Chem.107, 633 (1976).

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Botto, I.L., Baran, E.J. & Aymonino, P.J. Die IR-Spektren einiger Metavanadate mit tetraedrischer Vanadin-Koordination. Monatshefte für Chemie 107, 1127–1139 (1976). https://doi.org/10.1007/BF00903799

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