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Synthesis of organoantimony compounds by exchange between organomercury compounds and antimony halides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the reactions of bis-cis-2-chlorovinylmercury with antimony penta- and trichlorides, dichlorotris-cis-2-chlorovinylantimony and tris-cis-2-chlorovinylstibine are formed, respectively. The substances described earlier as dichlorotris-cis-2-chlorovinylantimony and tris-cis-2-chlorovinylstibine are the cis-trans-trans isomers.

  2. 2.

    The reactions of tris-cis-2-chlorovinylstibine with chlorine and bromine lead to the formation of dichloro- and dibromo-tris-cis-2-chlorovinylantimonys.

  3. 3.

    The trans isomers of the 2-chlorovinyl compounds of antimony react with liberation of acetylene at a lower concentration of alkali and at a lower temperature than the cis isomers.

  4. 4.

    Exchange reactions between antimony pentachloride and R2Hg provide a convenient method for the synthesis of aliphatic and aromatic compounds of formula R3SbCl2.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, A. E. Borisov & N. V. Novikova

Authors
  1. A. N. Nesmeyanov
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  2. A. E. Borisov
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  3. N. V. Novikova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1978–1982, September, 1969.

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Nesmeyanov, A.N., Borisov, A.E. & Novikova, N.V. Synthesis of organoantimony compounds by exchange between organomercury compounds and antimony halides. Russ Chem Bull 18, 1830–1833 (1969). https://doi.org/10.1007/BF00905817

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  • DOI: https://doi.org/10.1007/BF00905817

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