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Mass spectrometric investigation of carbohydrates

Communication 6. Mass spectra of 2,3,4,6-tetra-O-methyl-β-methyl-D-galactopyranoside and its deuteromethylated analogs

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The decomposition of 2,3,4,6-tetra-O-methyl-β-methyl-D-galactopyranoside and that of the previously studied 2,3,4,6-tetra-O-methyl-α-methyl-D-glucopyranoside proceed practically identically. This makes it possible to use the mass spectrometric data obtained for one methylated methylglucoside for the identification of its epimers as well.

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Literature cited

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Authors and Affiliations

  1. Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR, USSR

    N. K. Kochetkov, O. S. Chizhov & B. M. Zolotarev

  2. Scientific Research Institute of the Petroleum Industry, USSR

    N. K. Kochetkov, O. S. Chizhov & B. M. Zolotarev

Authors
  1. N. K. Kochetkov
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  2. O. S. Chizhov
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  3. B. M. Zolotarev
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Additional information

Moreover, the existence of such differences would open the way for a differentiation of epimeric monosaccharides according to their mass spectra.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 537–543, March, 1967.

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Kochetkov, N.K., Chizhov, O.S. & Zolotarev, B.M. Mass spectrometric investigation of carbohydrates. Russ Chem Bull 16, 520–525 (1967). https://doi.org/10.1007/BF00905984

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  • DOI: https://doi.org/10.1007/BF00905984

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