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Chemistry of acetals

Communication 18. Reactions of acetals with compounds containing a mobile hydrogen atom

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The new reaction of acetals of saturated and acetylenic aldehydes with β-diearbonyl compounds was studied for the case of acetoacetic ester and its homologs.

  2. 2.

    The structure of the alkoxy keto esters obtained was proved, and a mechanism with reaction via cyclic electron transfer is proposed.

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Literature cited

  1. S. S. Yufit and V. F. Kucherov, Izv. AN SSSR, Otd. khim. n.,1960, 1658.

  2. Zh. A. Krasnaya and V. F. Kucherov, Izv. AN SSSR, Ser. khim.,1965, 1070.

  3. S. S. Yufit and V. F. Kucherov, Izv. AN SSSR, Otd. khim. n.,1961, 1646.

  4. J. Klein and E. D. Bergmann, J. Amer. Chem. Soc.,79, 3452 (1957).

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  5. B. A. Rudenko and V. F. Kucherov, Dokl. AN SSSR,145, 577 (1962).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    S. S. Yufit, Zh. A. Krasnaya, T. S. Levchenko & V. F. Kucherov

Authors
  1. S. S. Yufit
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  2. Zh. A. Krasnaya
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  3. T. S. Levchenko
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  4. V. F. Kucherov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp, 132–138, January, 1967.

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Yufit, S.S., Krasnaya, Z.A., Levchenko, T.S. et al. Chemistry of acetals. Russ Chem Bull 16, 123–127 (1967). https://doi.org/10.1007/BF00907111

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  • DOI: https://doi.org/10.1007/BF00907111

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