Skip to main content
SpringerLink
Log in

Pulse radiolysis of aqueous solutions of sulfuric acid

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Using the method of pulse radiolysis in irradiated aqueous solutions of sulfuric acid, a short-lived optical absorption (maximum at 450 mμ due to the HSO4 (or SO −4 ) radical has been detected. The molar extinction coefficient of this product (∼1000 liter/mole · cm) and the velocity constant of the reaction between the OH radical and the HSO −4 (or SO 2−4 ) ion (∼106 liter/mole · sec) have been evaluated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. A. O. Allen, Eadiation Res.1, 85 (1954).

    Google Scholar 

  2. T. J. Sworski, Radiation Res.6, 645 (1957).

    Google Scholar 

  3. J. W. Boyle, Radiation Res.17, 427, 450 (1962).

    Google Scholar 

  4. L. T. Bugaenko, Khuan Guan'-lin', and N. A. Bakh, Dokl. AN SSSR,149, 1099 (1963).

    Google Scholar 

  5. A. K. Pikaev, P. Ya. Glazunov, and V. I. Spitsyn, Dokl. AN SSSR,150, 1077 (1963).

    Google Scholar 

  6. C. J. Hochanadel, Radiation Res.17, 286 (1962).

    Google Scholar 

  7. A. K. Pikaev and P. Ya. Glazunov, Izv. AN SSSR, Ser. Khim.,1964, 1944.

  8. A. K. Pikaev, G. K. Sibirskaya, G. G. Ryabchikova, and P. Ya. Glazunov, Kinetika i Kataliz,6, 41 (1965).

    Google Scholar 

  9. V. N. Shubin, V. A. Zhigunov, V. I. Zolotarevskii, and P. I. Dolin, Dokl. AN SSSR, (1965) (in thepress).

  10. P. Ya. Glazunov and A. K. Pikaev, Dokl. AN SSSR,130, 1051 (1960).

    Google Scholar 

  11. A. K. Pikaev, The Pulse Radiolysis of Water and Aqueous Solutions [in Russian], Nauka, Moscow,1965, p. 78.

    Google Scholar 

  12. P. N. Moorthy and J. J. Weiss, Advances in Chemistry Series50, 180 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, USSR

    A. K. Pikaev & V. I. Zolotarevskii

  2. Insitute of Electrochemistry, Academy of Sciences of the USSR, USSR

    A. K. Pikaev & V. I. Zolotarevskii

Authors
  1. A. K. Pikaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Zolotarevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp, 188–190, January, 1967.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pikaev, A.K., Zolotarevskii, V.I. Pulse radiolysis of aqueous solutions of sulfuric acid. Russ Chem Bull 16, 181–182 (1967). https://doi.org/10.1007/BF00907128

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00907128

Keywords

Search

Navigation