Summary
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1.
On the basis of formal use of the law of mass action and the adsorption equilibrium we have derived equations for the adsorption isotherms of binary mixtures.
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2.
Experimental data of adsorption of mixtures of vapors agree well with our equations.
Literature cited
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D. J. Hitchcock, J. Amer. Chem. Soc.48, 2870 (1926).
Ja. Zeldovich, Acta Phys. Chim. URSS1, 961 (1934).
B. F. Bering and V. V. Serpinskii, Izv. AN SSSR, Otd. khim. n. 1952, 997.
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Elovin, S.Y., Larionov, O.G. The application of the mass action law to adsorption equilibria. Russ Chem Bull 11, 491–493 (1962). https://doi.org/10.1007/BF00909556
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DOI: https://doi.org/10.1007/BF00909556