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Das Schwingungsspektrum von Magnesium-orthovanadat

The vibrational spectrum of magnesium orthovanadate

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The infrared and laser-Raman spectra of crystalline Mg3(VO4)2 are reported and a factor group analysis for the full lattice is presented to support the discussion. The 1,000 to 600 cm−1 region of the spectrum is essentially related to internal (stretching) modes of the greatly distorted VO4 tetrahedra, whereas the bands in the low frequency region must be assigned to complex vibrations originating in the interaction of the bending vibrations of the tetrahedral groups with the external modes.

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Authors and Affiliations

  1. Cátedra de Química Inorgánica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calle 47 esq. 115, La Plata, Argentinien

    Enrique J. Baran

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  1. Enrique J. Baran
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Mit 2 Abbildungen

12. Mitteilung der Reihe “Orthovanadate und verwandte Verbindungen”. 11. Mitt.:E. J. Baran, L. A. Gentil, J. C. Pedregosa undP. J. Aymonino, Z. anorg. allg. Chem., im Druck.

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Baran, E.J. Das Schwingungsspektrum von Magnesium-orthovanadat. Monatshefte für Chemie 106, 1–11 (1975). https://doi.org/10.1007/BF00914494

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  • DOI: https://doi.org/10.1007/BF00914494

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