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Complex of aluminum borohydride with calcium borohydride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of Al(BH4)3 with the unsolvated Ca(BH4)2 gave the complex Ca(BH4)2·Al(BH4)3, which is stable at room temperature; its density and IR spectrum are given.

  2. 2.

    Ca(BH4)2·Al(BH4)3 decomposes completely into the component borohydrides when heated in vacuo or when treated with donor solvents. The complex apparently has the structure [CaBH4]+[Al(BH4)4]− after treatment with octane.

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Literature cited

  1. Metallgesellschaft, British Patent 840, 572 (1960).

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    L. V. Titov & E. R. Eremin

Authors
  1. L. V. Titov
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  2. E. R. Eremin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1188–1189, May, 1975.

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Titov, L.V., Eremin, E.R. Complex of aluminum borohydride with calcium borohydride. Russ Chem Bull 24, 1095–1096 (1975). https://doi.org/10.1007/BF00922975

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  • DOI: https://doi.org/10.1007/BF00922975

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