Skip to main content
SpringerLink
Log in

Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A study was made of the reaction for replacing the hydrogen atom, attached to the silicon in triorganylsilanes, by the chlorine atom when reaction is with chlorobenzene in the presence of colloidal nickel as the catalyst. A probable scheme of the reaction mechanism is given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. Yu. I. Khudobin, B. N. Dolgov, and N. P. Kharitonov, in: Chemistry and Practical Application of Organosilicon Compounds [in Russian], Izd. AN SSSR (1961), No. 6, p. 155.

  2. Yu. I. Khudobin, M. G. Voronkov, and N. P. Kharitonov, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 598 (1967).

  3. Yu. I. Khudobin, M. G. D'yachenko, N. P. Kharitonov, and P. A. Vasil'eva, Zh. Obshch. Khim.,38, 187 (1968).

    Google Scholar 

  4. Yu. I. Khudobin, N. A. Sergeeva, and N. P. Kharatonov, Zh. Obshch. Khim.,38, 412 (1968).

    Google Scholar 

  5. V. Bazant, V. Chvalovsky, and J. Rathhousky, Organosilicon Compounds, Prague (1965), Vol. 1, Part 1, pp. 132, 180, 237, 353, 506, 521, 558, 608, 665, 684; Vol. 2, Part 2, pp. 50, 80, 81, 125, 126.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences of the USSR, Leningrad

    Yu. I. Khudobin, N. A. Andreeva, N. P. Kharitonov & M. G. Voronkov

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    Yu. I. Khudobin, N. A. Andreeva, N. P. Kharitonov & M. G. Voronkov

Authors
  1. Yu. I. Khudobin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Andreeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. P. Kharitonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 856–859, April, 1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khudobin, Y.I., Andreeva, N.A., Kharitonov, N.P. et al. Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene. Russ Chem Bull 23, 820–822 (1974). https://doi.org/10.1007/BF00923508

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00923508

Keywords

Search

Navigation