Conclusions
A study has been made of the isotopic structures of theν 1 andν 3 IR absorption bands of dichlorocarbene and dichlorosilylene, each stabilized in an Ar matrix at 15–20°K. A determination has been made of the valence angles, force constants, and vibration frequencies,ν 1,ν 2, andν 3 for various isotopic CCl2 and SiCl2 molecules.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2236–2242, October, 1977.
The authors would like to thank S. P. Kolesnikov and B. L. Perl'mutter who supplied the C4H8O2·GeCl2 complex, and E. A. Chernyshev, N. G. Komalenkova and S. A. Bashkirova who supplied the Si2Cl6.
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Svyatkin, V.A., Mal'tsev, A.K. & Nefedov, O.M. Vibrational spectra and structures of CCl2 and SiCl2 molecules stabilized in an Ar matrix. Russ Chem Bull 26, 2072–2078 (1977). https://doi.org/10.1007/BF00923623
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DOI: https://doi.org/10.1007/BF00923623