Conclusions
-
1.
During the process of cycloamination of amino alcohols in the presence of a Co/Al2O3 catalyst, compounds of Co+ soluble in the liquid phase and methanol are formed.
-
2.
The soluble compounds do not catalyze the process, which is heterogeneous over its entire extent. In the absence of a solid catalyst they break down, apparently playing the role of intermediate compounds.
-
3.
As a result of the reaction, a readily oxidized form of Co is produced, capable of dissolving in 0.1 N iodine solution. It was suggested that it is formed as a result of repeated participation of Co in the process of synthesis and decomposition of the complex.
-
4.
N-2-Hydroxypropylethylenediamine forms 2-methylpiperazine in the system of pentacyanocobaltate and cobalt acetate,α,α′-dipyridyl, and NaBH4.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
E. I. Karpeiskaya, V. A. Ferapontov, A. A. Tolstopyatova, and A. A. Balandin, Izv. Akad. Nauk SSSR, Ser. Khim., 1508 (1968).
E. I. Karpeiskaya and L. S. Gorshkova, ibid., 2716 (1970).
E. I. Karpeiskaya, Proceedings of the XIIIth International Conference on Coordination Chemistry, No. 209, Krakov (1970).
M. M. Jones, Ligand Reactivity and Catalysis, New York-London (1968).
E. I. Karpeiskaya, Yu. N. Kukushkin, V. A. Trofimov, and I. P. Yakovlev, Zh. Neorg. Khim.,17, 2189 (1972).
J. Kwiatek, Catalysis Rev.,1, 37 (1967).
Y. Henrici-Olive and S. Olive, Chimia,20, 27 (1966).
W. C. Drinkard, H. F. Bauer, and J. C. Bailar, J. Am. Chem. Soc.,82, 2992 (1960).
E. I. Karpeiskaya, Yu. N. Kukushkin, V. A. Trofimov, and I. P. Yakovlev, Zh. Neorg. Khim.,16, 1960 (1971).
H. A. Latinen and L. W. Burdett, Analyt. Chem.,27, 1268 (1951).
A. A. Balandin, V. A. Ferapontov, E. I. Karpeiskaya, and L. S. Gorshkova, Dokl. Akad. Nauk SSSR,170, 589 (1966).
A. P. Karnaukhov, L. M. Kefeli, I. D. Ratner, and L. V. Tsikaeva, Methods of Investigation of Catalysts and Catalytic Reactions [in Russian], Vol. 2, Novosibirsk (1965), p. 185.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 338–344, February, 1974.
Rights and permissions
About this article
Cite this article
Karpeiskaya, E.I., Kukushkin, Y.N., Trofimov, V.A. et al. Interaction of the catalyst and substrate in the cycloamination of amino alcohols. Russ Chem Bull 23, 307–312 (1974). https://doi.org/10.1007/BF00924675
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00924675