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Radical gas-phase decomposition of nitrobenzene derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Kinetic characteristics for C-N bond rupture, the first elementary step in gas-phase decomposition, have been estimated for 13 derivatives of nitrobenzene.

  2. 2.

    A correlation equation relating molecular structures and rate constants has been developed for p- and m-derivatives with donor-type substituents.

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Literature cited

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. G. Matveev, V. V. Dubikhin & G. M. Nazin

Authors
  1. V. G. Matveev
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  2. V. V. Dubikhin
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  3. G. M. Nazin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 783–786, April, 1978.

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Matveev, V.G., Dubikhin, V.V. & Nazin, G.M. Radical gas-phase decomposition of nitrobenzene derivatives. Russ Chem Bull 27, 675–678 (1978). https://doi.org/10.1007/BF00925282

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  • DOI: https://doi.org/10.1007/BF00925282

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