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Lyotropic mesophase formation in PVA/imogolite mixture

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Summary

The mesophase formation was observed in the ternary system consisting of a solvent, a rigid rod solute (imogolite), and a randomly coiled polymer chain (poly(vinyl alcohol); PVA). Although the mesophase formation in this system seems to follow qualitatively the scheme presented by Flory, no marked segregation of the two solute component was confirmed. The physical properties of the composite film prepared from this ternary system were also examined.

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References

  1. N. Donkai, H. Inagaki, K. Kajiwara, H. Urakawa, and M. Schmidt,Makromol. Chem.,186, 2623 (1985)

    Google Scholar 

  2. K. Kajiwara, N. Donkai, T. Fujiyoshi, T. Hiragi, H. Urakawa, and H. Inagaki,Bull. Inst. Chem. Res., Kyoto Univ.,63, 320 (1985)

    Google Scholar 

  3. K. Kajiwara, N. Donkai, Y. Hiragi, H. Inagaki,Makromol. Chem.,187, 2883 (1986)

    Google Scholar 

  4. K. Kajiwara, N. Donkai, Y. Fujiyoshi, H. Inagaki,Makromol. Chem.,187, 2895 (1986)

    Google Scholar 

  5. L. Onsager,Ann. N. Y. Acad. Sci.,51, 627 (1949)

    Google Scholar 

  6. P. J. Flory,Proc. R. Soc. (London),A234, 73 (1956)

    Google Scholar 

  7. N. Donkai, H. Inagaki, K. Kajiwara; in “Wood Processing and Utilization” (ed. by J. F. Kennedy, G.O. Phillips, P. A. Williams), Ellis Horwood, Chichester, 1989, p.285

    Google Scholar 

  8. H. Hoshino, M. Yamana, N. Donkai, V. Sinigersky, K. Kajiwara, T. Miyamoto, H. Inagaki,Polymer Bulletin, to appear

  9. N. Donkai, H. Hoshino, K. Kajiwara, T. Miyamoto,Makromol. Chem., to appear

  10. P. J. Flory,Macromolecules,11, 1138 (1978)

    Google Scholar 

  11. Polymer Handbook” (ed. by J. Brandrup, E. H. Immergut), J. Wiley & Sons, New York, 1975

    Google Scholar 

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Hoshino, H., Ito, T., Donkai, N. et al. Lyotropic mesophase formation in PVA/imogolite mixture. Polymer Bulletin 29, 453–460 (1992). https://doi.org/10.1007/BF00944844

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  • DOI: https://doi.org/10.1007/BF00944844

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