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Effect of phase composition of palladium-ruthenium membrane catalyst on selectivity of dehydrolinalool hydrogenation

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

When the hydrogenation of dehydrolinalool to linalool is run on a Pd alloy containing 6 wt.% of Ru, which is lean in the α-hydrogen phase, the selectivity is much greater than when the amount of the β-hydrogen phase is greater. A high selectivity of the hydrogenation is achieved by reducing to a definite limit the amount of hydrogen in the membrane catalyst without using inhibitors of the side reactions, which can contaminate the hydrogenation products.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    V. M. Gryaznov, A. P. Maganyuk, A. N. Karavanov & V. A. Naumov

  2. Patrice Lumumba People's Friendship University, USSR

    V. M. Gryaznov, A. P. Maganyuk, A. N. Karavanov & V. A. Naumov

Authors
  1. V. M. Gryaznov
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  2. A. P. Maganyuk
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  3. A. N. Karavanov
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  4. V. A. Naumov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 926–928, April, 1984.

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Gryaznov, V.M., Maganyuk, A.P., Karavanov, A.N. et al. Effect of phase composition of palladium-ruthenium membrane catalyst on selectivity of dehydrolinalool hydrogenation. Russ Chem Bull 33, 853–855 (1984). https://doi.org/10.1007/BF00947853

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  • DOI: https://doi.org/10.1007/BF00947853

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