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Mechanism of homolysis of M-C bonds in group IVB organometallic derivatives of o-semiquinones

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Disappearance of the free valence in organometallic derivatives of o-semiquniones with IVB group metals linked with elimination of one of the radicals on the IVB group element, proceeds by a bimolecular mechanism with participation of an external acceptor of the radical. The case in which a stable radical is formed as a result of elimination constitutes an exception.

  2. 2.

    Examples of acceptors contributing to radical elimination are atoms of metals, organometallic and organic radicals, and neutral molecules.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gorkii

    G. A. Razuvaev, G. A. Abakumov, P. Ya. Bayushkin, V. A. Tsaryapkin & V. K. Cherkasov

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  1. G. A. Razuvaev
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  2. G. A. Abakumov
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  3. P. Ya. Bayushkin
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  4. V. A. Tsaryapkin
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  5. V. K. Cherkasov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2098–2105, September, 1984.

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Razuvaev, G.A., Abakumov, G.A., Bayushkin, P.Y. et al. Mechanism of homolysis of M-C bonds in group IVB organometallic derivatives of o-semiquinones. Russ Chem Bull 33, 1915–1922 (1984). https://doi.org/10.1007/BF00948642

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  • DOI: https://doi.org/10.1007/BF00948642

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