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Kinetics and mechanism of thermal decomposition of hydroxylammonium perchlorate and its complex with hydroxylamine

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In its initial stages, the decomposition of hydroxylammonium perchlorate involves dissociation of the salt followed by decomposition of a complex of hydroxylamine with hydroxylammonium perchlorate. At elevated temperatures the reaction involving hydroxylamine molecules not bound into complexes plays an increasing part.

  2. 2.

    As hydroxylammonium perchlorate decomposes, the leading stage changes. The crucial reaction becomes oxidation of NH3OH+ by perchloric acid, leading to autocatalysis of the process.

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    Yu. I. Rubtsov, E. S. Rumyantsev, L. P. Andrienko, V. A. Rafeev, G. N. Lyubimova & G. B. Manelis

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  1. Yu. I. Rubtsov
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  2. E. S. Rumyantsev
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  3. L. P. Andrienko
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  4. V. A. Rafeev
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  5. G. N. Lyubimova
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  6. G. B. Manelis
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1463–1469, July, 1980.

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Rubtsov, Y.I., Rumyantsev, E.S., Andrienko, L.P. et al. Kinetics and mechanism of thermal decomposition of hydroxylammonium perchlorate and its complex with hydroxylamine. Russ Chem Bull 29, 1011–1017 (1980). https://doi.org/10.1007/BF00949144

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  • DOI: https://doi.org/10.1007/BF00949144

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