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Transbutylation of aromatic hydrocarbons by 3,6-di-tert-butylpyrocatechol in presence of su lfuric acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The transbutylation of the aromatic substrate takes place in the system 3,6-di-tert-butylpyrocatechol-H2SO4-aromatic hydrocarbon.

  2. 2.

    The efficiency of transbutylation depends on the basicity of the aromatic hydrocarbon and on the presence in the system of bases that are capable of acting as competitive proton binders.

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Literature cited

  1. A. B. Vol'-épshtein and S. G. Gagarin, Catalytic Transformations of Alkylphenols [in Russian], Khimiya, Moscow (1973), p. 9.

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  3. V. V. Ershov, G. A. Nikiforov, and A. A. Volod'kin, Sterically Hindered Phenols [in Russian], Khimiya, Moscow (1972), p. 32.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, N. L. Komissarova & V. V. Ershov

Authors
  1. V. B. Vol'eva
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  2. I. A. Novikova
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  3. I. S. Belostotskaya
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  4. N. L. Komissarova
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  5. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2128–2130, September, 1981.

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Vol'eva, V.B., Novikova, I.A., Belostotskaya, I.S. et al. Transbutylation of aromatic hydrocarbons by 3,6-di-tert-butylpyrocatechol in presence of su lfuric acid. Russ Chem Bull 30, 1748–1750 (1981). https://doi.org/10.1007/BF00949489

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  • DOI: https://doi.org/10.1007/BF00949489

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