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Asymmetric amination of butadiene by secondary amines, catalyzed-by low-valence nickel chiral complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It was shown that it is theoretically possible to obtain optically active unsaturated amines by reacting butadiene with the simpler secondary amines in the presence of chiral Ni-containing metal complex catalysts.

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Literature cited

  1. U. M. Dzhemilev, A. Z. Yakupova, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2379.

  2. U. M. Dzhemilev, A. Z. Yakupova, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 1068.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. N. Fakhretdinov, A. G. Telin, G. A. Tolstikov, A. A. Panasenko & E. V. Vasil'eva

Authors
  1. U. M. Dzhemilev
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  2. R. N. Fakhretdinov
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  3. A. G. Telin
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  4. G. A. Tolstikov
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  5. A. A. Panasenko
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  6. E. V. Vasil'eva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2771–2777, December, 1980.

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Dzhemilev, U.M., Fakhretdinov, R.N., Telin, A.G. et al. Asymmetric amination of butadiene by secondary amines, catalyzed-by low-valence nickel chiral complexes. Russ Chem Bull 29, 1943–1948 (1980). https://doi.org/10.1007/BF00949662

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  • DOI: https://doi.org/10.1007/BF00949662

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