Skip to main content
Log in

Study of reactivity of neptunium ions toward oh radicals in perchloric acid solutions by pulse radiolysis method

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The rate constants for the reactions of OH radicals with Np(IV) and Np(V) ions in aqueous perchloric acid solutions are practically independent of the acidity of the medium and are quite high, in order to exclude the recombination of the OH radicals in the presence of these ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. M. V. Vladimirova, I. A. Kulikov, A. S. Milovanova, and A. A. Ryabova, Radiokhimiya21, 272 (1979).

    Google Scholar 

  2. M. V. Vladimirova, I. A. Kulikov, A. A. Ryabova, and A. S. Milovanova, Radiokhimiya18, 172 (1976).

    Google Scholar 

  3. A. K. Pikaev, G. K. Sibirskaya, E. M. Shirshov, P. Ya. Glazunov, and V. I. Spitsyn Dokl. Akad. Nauk SSSR,200, 383 (1971).

    Google Scholar 

  4. A. K. Pikaev, V. P. Shilov, and A. M. Fedoseev, Dokl. Akad. Nauk SSSR,260, 1407 (1981).

    Google Scholar 

  5. K. Myuzikas and M. Marto, Radiokhimiya,20, 253 (1978).

    Google Scholar 

  6. P. R. V. Rao, S. V. Bagamde, V. V. Ramakrishna, and S. K. Patil, J. Inorg. Nucl. Chem.,40, 339 (1978).

    Google Scholar 

  7. Farhataziz and A. B. Ross, Selected Specific Rates of Reactions of Transients from Water in Aqueous Solutions. III. Hydroxyl Radical and Perhydroxyl Radical and Their Radical Ions, NSRDS-NBS 59, Washington (1977).

  8. V. M. Berdnikov, Zh. Fiz. Khim.,47, 2753 (1973).

    Google Scholar 

  9. A. K. Pikaev, V. P. Shilov, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,232, 387 (1977).

    Google Scholar 

  10. A. K. Pikaev, Pulse Radiolysis of Water and Aqueous Solutions [in Russian], Nauka, Moscow (1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 940–942, April, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shilov, V.P., Fedoseev, A.M. & Pikaev, A.K. Study of reactivity of neptunium ions toward oh radicals in perchloric acid solutions by pulse radiolysis method. Russ Chem Bull 31, 832–834 (1982). https://doi.org/10.1007/BF00950034

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950034

Keywords

Navigation