Conclusions
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1.
The pseudo-first-order reaction rate constants for the thallation of substituted carboranes were determined.
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2.
The thallation rate of methyl-o-carborane is second order in thallium tris(trifluoroacetate) and first order in carborane.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1428–1431, June, 1981.
The authors express their gratitude to A. D. Ryabov for assistance in discussing the results.
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Usyatinskii, A.Y., Bregadze, V.I., Shcherbina, T.M. et al. Kinetics and mechanism of thallation of carboranes. Russ Chem Bull 30, 1148–1150 (1981). https://doi.org/10.1007/BF00950322
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DOI: https://doi.org/10.1007/BF00950322