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Reaction of dichlorophosphorylimidophosphorus trichloride with nucleophilic reagents

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

When dichlorophosphorylimidophosphorus trichloride is reacted with nucleophilic reagents (phenols, dialkylamines, and their trimethylsilyl derivatives), the first to be replaced is the chloride atom on the imido P atom. As the result of further reaction with phenol the substitution at the imido P atom continues, while when reaction is with diethylamine or diethylaminotrimethylsilane the chlorine atom on the phosphoryl P atom is replaced.

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Literature cited

  1. L. Seglin, M. Lutz, and H. Stange, U.S. Patent 3, 231, 327 (1961); Chem. Abstr.,64, 10810d (1966).

    Google Scholar 

  2. M. Becke-Goehrinĝ, T. Mann, and H. D. Euler, Chem. Ber.,94, 193 (1961); E. S. Levchenko and E. I. Sheinkman, Zh. Obshch. Khim.,34, 1145 (1964).

    Google Scholar 

  3. M. Becke-Goehring, A. Debo, E. Fluck, and W. Goetze, Chem. Ber.,94, 1383 (1961).

    Google Scholar 

  4. V. V. Klreev, G. S. Kolesnikov, and S. S. Titov, Zh. Obshch. Khim.,40, 2015 (1970); A. A. Khodak, V. A. Gilyarov, T. M. Shcherbina, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim.,1979, 1884.

    Google Scholar 

  5. A. Ya. Yakubovich, N. I. Shvetsov, L. V. Lebedeva, and V. S. Yakubovich, Zh. Neorgan. Khim.,8, 534, 1831 (1963); L. Riesel, M. Willfahrt, W. Grosse, P. Kindscherowsky, A. A. Chodak (Khodak), V. A. Giljarov (Gilyarov), and M. I. Kabatschnik (Kabachnik), Z. Anorg. Allgem. Chem.,435, 61 (1977).

    Google Scholar 

  6. G. Bulloch and R. Keat, Inorg. Chim. Acta,33, 245 (1979).

    Google Scholar 

  7. L. Riesel and P. Somieski, Z. Anorg. Allgem. Chem.,411, 148 (1970).

    Google Scholar 

  8. V. A. Shokol. G. A. Golik, V. T. Tsyba, and G. I. Derkach, Zh. Obshch. Khim.,40, 931 (1970).

    Google Scholar 

  9. V. A. Gilyarov and M. I. Kabachnik, Zh. Obshch. Khim.,42, 2184 (1972).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. A. Khodak, V. A. Gilyarov & M. I. Kabachnik

Authors
  1. A. A. Khodak
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  2. V. A. Gilyarov
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  3. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2379–2386, October, 1980.

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Khodak, A.A., Gilyarov, V.A. & Kabachnik, M.I. Reaction of dichlorophosphorylimidophosphorus trichloride with nucleophilic reagents. Russ Chem Bull 29, 1694–1701 (1980). https://doi.org/10.1007/BF00951238

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  • DOI: https://doi.org/10.1007/BF00951238

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