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Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead toβ-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. S. Zefirov, A. S. Koz'min, V. D. Sorokin, V. V. Zhdankin, Yu. N. Studnev & A. V. Fokin

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. S. Zefirov, A. S. Koz'min, V. D. Sorokin, V. V. Zhdankin, Yu. N. Studnev & A. V. Fokin

Authors
  1. N. S. Zefirov
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  2. A. S. Koz'min
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  3. V. D. Sorokin
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  4. V. V. Zhdankin
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  5. Yu. N. Studnev
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  6. A. V. Fokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 389–391, February, 1985.

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Zefirov, N.S., Koz'min, A.S., Sorokin, V.D. et al. Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins. Russ Chem Bull 34, 356–358 (1985). https://doi.org/10.1007/BF00951286

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  • DOI: https://doi.org/10.1007/BF00951286

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