Conclusions
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1.
Organomercury compounds react with the cluster Pd10(CO)12(PBu3)6 to form mononuclearσ-complexes of palladium.
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2.
The insertion of a fragment Pd(CO)L in the course of reaction of organomercury compounds with Pd(0) complexes has been observed for the first time.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 923–926, April, 1983.
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Bashilov, V.V., Mednikov, E.G., Sokolov, V.I. et al. Redox-demercuration by the cluster Pd10(CO)12(PBu3)6 . Russ Chem Bull 32, 837–840 (1983). https://doi.org/10.1007/BF00953490
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DOI: https://doi.org/10.1007/BF00953490